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Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles

Publication ,  Journal Article
Crumbliss, AL; Batinić-Haberle, I; Spasojević, I
Published in: Pure and Applied Chemistry
January 1, 1996

An investigation of second coordination shell complexation of ferrioxamine B by crown ethers, natural ionophores, and other macrocycles through host-guest complexation of the pendant protonated amine group is presented. The influence of guest structure, host structure, solvation shell, and counter ion on host-guest assembly stability is discussed. Application of this form of molecular recognition to bulk liquid membrane transport of a stable metal complex is also presented. The significance of ionophore recognition of a metal complex in the context of iron bioavailability is discussed.

Duke Scholars

Published In

Pure and Applied Chemistry

DOI

ISSN

0033-4545

Publication Date

January 1, 1996

Volume

68

Issue

6

Start / End Page

1225 / 1230

Related Subject Headings

  • General Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Crumbliss, A. L., Batinić-Haberle, I., & Spasojević, I. (1996). Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles. Pure and Applied Chemistry, 68(6), 1225–1230. https://doi.org/10.1351/pac199668061225
Crumbliss, A. L., I. Batinić-Haberle, and I. Spasojević. “Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles.” Pure and Applied Chemistry 68, no. 6 (January 1, 1996): 1225–30. https://doi.org/10.1351/pac199668061225.
Crumbliss AL, Batinić-Haberle I, Spasojević I. Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles. Pure and Applied Chemistry. 1996 Jan 1;68(6):1225–30.
Crumbliss, A. L., et al. “Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles.” Pure and Applied Chemistry, vol. 68, no. 6, Jan. 1996, pp. 1225–30. Scopus, doi:10.1351/pac199668061225.
Crumbliss AL, Batinić-Haberle I, Spasojević I. Molecular recognition of stable metal complexes through second-sphere coordination by macrocycles. Pure and Applied Chemistry. 1996 Jan 1;68(6):1225–1230.
Journal cover image

Published In

Pure and Applied Chemistry

DOI

ISSN

0033-4545

Publication Date

January 1, 1996

Volume

68

Issue

6

Start / End Page

1225 / 1230

Related Subject Headings

  • General Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences