Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements
Publication
, Journal Article
Chabinyc, ML; Craig, SL; Regan, CK; Brauman, JI
Published in: Science (New York, N.Y.)
March 1998
Nucleophilic displacement reactions (the SN2 reaction) of ions in the gas phase are a prototypical reaction system that allows a study of dynamics, mechanisms, and structure-energy relations. This article reviews aspects of the kinetics (especially the applicability of statistical reaction rate theory), the relation of structure and reactivity, and the effects of small numbers of solvent molecules on the reaction and compares the behavior of the ionic reaction in the gas phase with that in solution.
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Published In
Science (New York, N.Y.)
DOI
EISSN
1095-9203
ISSN
0036-8075
Publication Date
March 1998
Volume
279
Issue
5358
Start / End Page
1882 / 1886
Related Subject Headings
- General Science & Technology
Citation
APA
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ICMJE
MLA
NLM
Chabinyc, M. L., Craig, S. L., Regan, C. K., & Brauman, J. I. (1998). Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements. Science (New York, N.Y.), 279(5358), 1882–1886. https://doi.org/10.1126/science.279.5358.1882
Chabinyc, M. L., S. L. Craig, C. K. Regan, and J. I. Brauman. “Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements.” Science (New York, N.Y.) 279, no. 5358 (March 1998): 1882–86. https://doi.org/10.1126/science.279.5358.1882.
Chabinyc ML, Craig SL, Regan CK, Brauman JI. Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements. Science (New York, NY). 1998 Mar;279(5358):1882–6.
Chabinyc, M. L., et al. “Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements.” Science (New York, N.Y.), vol. 279, no. 5358, Mar. 1998, pp. 1882–86. Epmc, doi:10.1126/science.279.5358.1882.
Chabinyc ML, Craig SL, Regan CK, Brauman JI. Gas-phase ionic reactions: dynamics and mechanism of nucleophilic displacements. Science (New York, NY). 1998 Mar;279(5358):1882–1886.
Published In
Science (New York, N.Y.)
DOI
EISSN
1095-9203
ISSN
0036-8075
Publication Date
March 1998
Volume
279
Issue
5358
Start / End Page
1882 / 1886
Related Subject Headings
- General Science & Technology