Branching ratios in activated systems
Publication
, Journal Article
Craig, SL; Zhong, M; Choo, B; Brauman, JI
Published in: Journal of Physical Chemistry A
January 2, 1997
Branching between reaction channels in activated systems is often observed to vary with changes in the potential energy surface as Δln(k1/k2) ∝ Δ(ΔE‡1 - ΔE‡2). RRKM calculations demonstrate that in many, but not all, cases the log-linear relationship accurately describes branching in nonthermal distributions of reactants with energies well above the threshold for reaction. The origin of this relationship and conditions necessary for its validity can be understood in terms of quantum RRK theory.
Duke Scholars
Published In
Journal of Physical Chemistry A
DOI
ISSN
1089-5639
Publication Date
January 2, 1997
Volume
101
Issue
1
Start / End Page
19 / 24
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
Citation
APA
Chicago
ICMJE
MLA
NLM
Craig, S. L., Zhong, M., Choo, B., & Brauman, J. I. (1997). Branching ratios in activated systems. Journal of Physical Chemistry A, 101(1), 19–24. https://doi.org/10.1021/jp961665j
Craig, S. L., M. Zhong, B. Choo, and J. I. Brauman. “Branching ratios in activated systems.” Journal of Physical Chemistry A 101, no. 1 (January 2, 1997): 19–24. https://doi.org/10.1021/jp961665j.
Craig SL, Zhong M, Choo B, Brauman JI. Branching ratios in activated systems. Journal of Physical Chemistry A. 1997 Jan 2;101(1):19–24.
Craig, S. L., et al. “Branching ratios in activated systems.” Journal of Physical Chemistry A, vol. 101, no. 1, Jan. 1997, pp. 19–24. Scopus, doi:10.1021/jp961665j.
Craig SL, Zhong M, Choo B, Brauman JI. Branching ratios in activated systems. Journal of Physical Chemistry A. 1997 Jan 2;101(1):19–24.
Published In
Journal of Physical Chemistry A
DOI
ISSN
1089-5639
Publication Date
January 2, 1997
Volume
101
Issue
1
Start / End Page
19 / 24
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics