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Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes

Publication ,  Journal Article
Zhao, J; Henkens, RW; Stonehuerner, J; O'Daly, JP; Crumbliss, AL
Published in: Journal of Electroanalytical Chemistry
June 10, 1992

The reduction of H2O2 on horseradish peroxidase (HRP) and horseradish peroxidase-gold sol (HRP-Au) modified electrodes has been studied with and without an electron transfer mediator. The amplification effect owing to the enzyme-catalyzed turnover of substrate facilitates our observation that HRP immobilized on colloidal gold and then deposited on a flat electrode surface can be reduced at a convenient rate at 0 V (Ag/AgCl) without an electron transfer mediator. Possible mechanisms and potential applications are discussed. © 1992.

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Published In

Journal of Electroanalytical Chemistry

DOI

ISSN

0022-0728

Publication Date

June 10, 1992

Volume

327

Issue

1-2

Start / End Page

109 / 119

Related Subject Headings

  • Energy
 

Citation

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Zhao, J., Henkens, R. W., Stonehuerner, J., O’Daly, J. P., & Crumbliss, A. L. (1992). Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes. Journal of Electroanalytical Chemistry, 327(1–2), 109–119. https://doi.org/10.1016/0022-0728(92)80140-Y
Zhao, J., R. W. Henkens, J. Stonehuerner, J. P. O’Daly, and A. L. Crumbliss. “Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes.” Journal of Electroanalytical Chemistry 327, no. 1–2 (June 10, 1992): 109–19. https://doi.org/10.1016/0022-0728(92)80140-Y.
Zhao J, Henkens RW, Stonehuerner J, O’Daly JP, Crumbliss AL. Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes. Journal of Electroanalytical Chemistry. 1992 Jun 10;327(1–2):109–19.
Zhao, J., et al. “Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes.” Journal of Electroanalytical Chemistry, vol. 327, no. 1–2, June 1992, pp. 109–19. Scopus, doi:10.1016/0022-0728(92)80140-Y.
Zhao J, Henkens RW, Stonehuerner J, O’Daly JP, Crumbliss AL. Direct electron transfer at horseradish peroxidase-colloidal gold modified electrodes. Journal of Electroanalytical Chemistry. 1992 Jun 10;327(1–2):109–119.
Journal cover image

Published In

Journal of Electroanalytical Chemistry

DOI

ISSN

0022-0728

Publication Date

June 10, 1992

Volume

327

Issue

1-2

Start / End Page

109 / 119

Related Subject Headings

  • Energy