Triallylphosphine plasma polymerization and reaction of the product with volatile transition metal compounds

Published

Journal Article

The plasma polymerization of triallylphosphine in order to form a crosslinked polymer thin film is described. The plasma polymer thin film has been characterized and shown to contain a high proporation of CC and P groups conserved from the monomer. The accessibilty of the phosphine groups has been demonstrated by reaction with O2, NO, Ni(CO)4, and Fe(CO)5. Reaction with O2, and NO results in a PO moiety formation. Reaction with the gaseous metal carbonyls results in fixation of the metal via complexation by the P groups as a result of exchange with CO ligand(s). This illustrates the utility of a ligand donor group containing plasma polymer as an avenue for the formation of a single phase transition metal containing plasma polymer. Copyright © 1992 John Wiley & Sons, Inc.

Full Text

Duke Authors

Cited Authors

  • Clymer, SD; Morosoff, NC; Crumbliss, AL

Published Date

  • January 1, 1992

Published In

Volume / Issue

  • 45 / 1

Start / End Page

  • 135 - 145

Electronic International Standard Serial Number (EISSN)

  • 1097-4628

International Standard Serial Number (ISSN)

  • 0021-8995

Digital Object Identifier (DOI)

  • 10.1002/app.1992.070450116

Citation Source

  • Scopus