Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes
Publication
, Journal Article
Pinault, FS; Crumbliss, AL
Published in: Journal of Organometallic Chemistry
July 28, 1981
Bis(dimethylglyoximato) complexes of cobalt(II), cobaloxime(II), under mild conditions initiate coupling of α,α,α-trihalomethylbenzenes to form PhCX2CX2Ph (X Cl), PhCXCXPh (X Cl, Br) and mixtures of halocobaloxime products. Stoichiometry, product distribution, and control experiments suggest that coupling may result from the decomposition of a highly unstable haloalkylcobaloxime intermediate, Co(dmgH)2(PhCX2)(S(CH3)2). A general mechanism for the formation of this intermediate and its decomposition to the observed products is presented. © 1981.
Duke Scholars
Published In
Journal of Organometallic Chemistry
DOI
ISSN
0022-328X
Publication Date
July 28, 1981
Volume
215
Issue
2
Start / End Page
229 / 239
Related Subject Headings
- Organic Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Pinault, F. S., & Crumbliss, A. L. (1981). Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes. Journal of Organometallic Chemistry, 215(2), 229–239. https://doi.org/10.1016/S0022-328X(00)80133-3
Pinault, F. S., and A. L. Crumbliss. “Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes.” Journal of Organometallic Chemistry 215, no. 2 (July 28, 1981): 229–39. https://doi.org/10.1016/S0022-328X(00)80133-3.
Pinault FS, Crumbliss AL. Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes. Journal of Organometallic Chemistry. 1981 Jul 28;215(2):229–39.
Pinault, F. S., and A. L. Crumbliss. “Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes.” Journal of Organometallic Chemistry, vol. 215, no. 2, July 1981, pp. 229–39. Scopus, doi:10.1016/S0022-328X(00)80133-3.
Pinault FS, Crumbliss AL. Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes. Journal of Organometallic Chemistry. 1981 Jul 28;215(2):229–239.
Published In
Journal of Organometallic Chemistry
DOI
ISSN
0022-328X
Publication Date
July 28, 1981
Volume
215
Issue
2
Start / End Page
229 / 239
Related Subject Headings
- Organic Chemistry
- 3403 Macromolecular and materials chemistry
- 3402 Inorganic chemistry
- 0399 Other Chemical Sciences
- 0305 Organic Chemistry
- 0302 Inorganic Chemistry