Cobaloxime(II)-initiated coupling of α,α,α-trihalomethylbenzenes
Journal Article (Journal Article)
Bis(dimethylglyoximato) complexes of cobalt(II), cobaloxime(II), under mild conditions initiate coupling of α,α,α-trihalomethylbenzenes to form PhCX CX Ph (X Cl), PhCXCXPh (X Cl, Br) and mixtures of halocobaloxime products. Stoichiometry, product distribution, and control experiments suggest that coupling may result from the decomposition of a highly unstable haloalkylcobaloxime intermediate, Co(dmgH) (PhCX )(S(CH ) ). A general mechanism for the formation of this intermediate and its decomposition to the observed products is presented. © 1981. 2 2 2 2 3 2
Full Text
Duke Authors
Cited Authors
- Pinault, FS; Crumbliss, AL
Published Date
- July 28, 1981
Published In
Volume / Issue
- 215 / 2
Start / End Page
- 229 - 239
International Standard Serial Number (ISSN)
- 0022-328X
Digital Object Identifier (DOI)
- 10.1016/S0022-328X(00)80133-3
Citation Source
- Scopus