Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins
Publication
, Journal Article
Dufour, MN; Crumbliss, AL; Johnston, G; Gaudemer, A
Published in: Journal of Molecular Catalysis
January 1, 1980
Cobalt(II), cobalt(III), and manganese(III) meso-tetraphenylporphins catalyse the oxygenation of simple alkyl-substituted indoles, the latter complex being the most active catalyst. Spectroscopic data (uv, n.m.r., e.s.r.) indicate that during the reaction catalysed by CoTPP, a ternary complex: O2CoTPPindole is formed initially. This complex is converted into indolenyl hydroperoxide, which decomposes to the final product under the influence of CoTPP. © 1980.
Duke Scholars
Published In
Journal of Molecular Catalysis
DOI
ISSN
0304-5102
Publication Date
January 1, 1980
Volume
7
Issue
2
Start / End Page
277 / 287
Related Subject Headings
- Physical Chemistry
- 4004 Chemical engineering
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0904 Chemical Engineering
- 0306 Physical Chemistry (incl. Structural)
- 0301 Analytical Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Dufour, M. N., Crumbliss, A. L., Johnston, G., & Gaudemer, A. (1980). Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins. Journal of Molecular Catalysis, 7(2), 277–287. https://doi.org/10.1016/0304-5102(80)85025-5
Dufour, M. N., A. L. Crumbliss, G. Johnston, and A. Gaudemer. “Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins.” Journal of Molecular Catalysis 7, no. 2 (January 1, 1980): 277–87. https://doi.org/10.1016/0304-5102(80)85025-5.
Dufour MN, Crumbliss AL, Johnston G, Gaudemer A. Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins. Journal of Molecular Catalysis. 1980 Jan 1;7(2):277–87.
Dufour, M. N., et al. “Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins.” Journal of Molecular Catalysis, vol. 7, no. 2, Jan. 1980, pp. 277–87. Scopus, doi:10.1016/0304-5102(80)85025-5.
Dufour MN, Crumbliss AL, Johnston G, Gaudemer A. Reaction of indoles with molecular oxygen catalyzed by metalloporphyrins. Journal of Molecular Catalysis. 1980 Jan 1;7(2):277–287.
Published In
Journal of Molecular Catalysis
DOI
ISSN
0304-5102
Publication Date
January 1, 1980
Volume
7
Issue
2
Start / End Page
277 / 287
Related Subject Headings
- Physical Chemistry
- 4004 Chemical engineering
- 3406 Physical chemistry
- 3402 Inorganic chemistry
- 0904 Chemical Engineering
- 0306 Physical Chemistry (incl. Structural)
- 0301 Analytical Chemistry