Synthesis of Sn doped CuO nanotubes from core-shell Cu/SnO(2) nanowires by the Kirkendall effect.
Published
Journal Article
Sn doped CuO nanotubes were synthesized by thermal oxidization of Cu/SnO(2) core-shell nanowires in air through the Kirkendall effect. The Cu/SnO(2) core-shell nanowires were sequentially electrodeposited by forming a SnO(2) shell followed by electrodeposition of the Cu core. After thermal treatment in air, the core-shell Cu/SnO(2) (13 +/- 2 nm thick shell on 128 +/- 15 nm in diameter core) nanowires were oxidized to form Sn doped CuO nanotubes with an average wall thickness and outer diameter of 54 nm and 176 nm, respectively. Room temperature I-V characterization indicated that the electrical resistivity of the nanostructures was 870 +/- 85 Omega cm. The methodology that was demonstrated is very general and could be used to synthesize coaxial SnO(2) shells with a variety of electrodeposited cores. In addition, doped metal oxide nanotubes can be readily synthesized by thermal oxidization of core-shell nanowires in air where the dopant content can be tuned by controlling the shell thickness through adjusting the deposition time.
Full Text
Duke Authors
Cited Authors
- Lai, M; Mubeen, S; Chartuprayoon, N; Mulchandani, A; Deshusses, MA; Myung, NV
Published Date
- July 2010
Published In
Volume / Issue
- 21 / 29
Start / End Page
- 295601 -
PubMed ID
- 20585175
Pubmed Central ID
- 20585175
Electronic International Standard Serial Number (EISSN)
- 1361-6528
International Standard Serial Number (ISSN)
- 0957-4484
Digital Object Identifier (DOI)
- 10.1088/0957-4484/21/29/295601
Language
- eng