Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection
Publication
, Journal Article
Cooper, SD; Moseley, MA; Pellizzari, ED
Published in: Analytical Chemistry
January 1, 1985
A method for calibrating an electron capture detector (ECD) for quantitative analysis of all 209 Individual polychlorinated biphenyl (PCB) congeners was developed by using a secondary standard containing 31 surrogate PCB congeners. By use of the relative response factors (RRFs) for 203 of the 209 PCBs determined by high resolution gas chromatography with ECD, RRFs were clustered to allow a commercially available PCB surrogate to represent a group of PCB congeners. With this statistically based approach, the calibration bias was <10% and the range of the percent relative standard deviation for the 31 groups of RRFs was 0–4.9%. © 1985, American Chemical Society. All rights reserved.
Duke Scholars
Published In
Analytical Chemistry
DOI
EISSN
1520-6882
ISSN
0003-2700
Publication Date
January 1, 1985
Volume
57
Issue
13
Start / End Page
2469 / 2473
Related Subject Headings
- Analytical Chemistry
- 0399 Other Chemical Sciences
- 0301 Analytical Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Cooper, S. D., Moseley, M. A., & Pellizzari, E. D. (1985). Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection. Analytical Chemistry, 57(13), 2469–2473. https://doi.org/10.1021/ac00290a010
Cooper, S. D., M. A. Moseley, and E. D. Pellizzari. “Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection.” Analytical Chemistry 57, no. 13 (January 1, 1985): 2469–73. https://doi.org/10.1021/ac00290a010.
Cooper SD, Moseley MA, Pellizzari ED. Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection. Analytical Chemistry. 1985 Jan 1;57(13):2469–73.
Cooper, S. D., et al. “Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection.” Analytical Chemistry, vol. 57, no. 13, Jan. 1985, pp. 2469–73. Scopus, doi:10.1021/ac00290a010.
Cooper SD, Moseley MA, Pellizzari ED. Surrogate Standards for the Determination of Individual Polychlorinated Biphenyls Using High-Resolution Gas Chromatography with Electron Capture Detection. Analytical Chemistry. 1985 Jan 1;57(13):2469–2473.
Published In
Analytical Chemistry
DOI
EISSN
1520-6882
ISSN
0003-2700
Publication Date
January 1, 1985
Volume
57
Issue
13
Start / End Page
2469 / 2473
Related Subject Headings
- Analytical Chemistry
- 0399 Other Chemical Sciences
- 0301 Analytical Chemistry