Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II)
Publication
, Journal Article
Wertz, DW; Moseley, MA
Published in: Inorganic Chemistry
January 1, 1980
The infrared and Raman spectra of 1, 5-cyclooctadiene (C8H12) (RhClC8H12)2, PtCl2C8H12, and PdCl2C8H12 have been recorded. Assignments are given for bands I and II, for olefinic CH wagging and rocking modes, and for metal-olefin stretching modes. On the basis of the shift in the frequencies of bands I and II and the CH wagging modes and the frequency of the symmetric metal-carbon stretching modes, the total interaction between the metal and olefin is Rh > Pt > Pd. The shift of the CH rocking modes and the frequency of the asymmetric metal-carbon modes are consistent with the ir interaction going in the order Pt > Rh > Pd with all complexes having extensive π interaction. © 1980, American Chemical Society. All rights reserved.
Duke Scholars
Published In
Inorganic Chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
January 1, 1980
Volume
19
Issue
3
Start / End Page
705 / 708
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry
Citation
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Wertz, D. W., & Moseley, M. A. (1980). Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II). Inorganic Chemistry, 19(3), 705–708. https://doi.org/10.1021/ic50205a025
Wertz, D. W., and M. A. Moseley. “Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II).” Inorganic Chemistry 19, no. 3 (January 1, 1980): 705–8. https://doi.org/10.1021/ic50205a025.
Wertz DW, Moseley MA. Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II). Inorganic Chemistry. 1980 Jan 1;19(3):705–8.
Wertz, D. W., and M. A. Moseley. “Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II).” Inorganic Chemistry, vol. 19, no. 3, Jan. 1980, pp. 705–08. Scopus, doi:10.1021/ic50205a025.
Wertz DW, Moseley MA. Vibrational Study of the Metal-Olefin Bond in 1, 5-Cyclooctadiene Complexes of Rhodium(I), Palladium(II), and Platinum(II). Inorganic Chemistry. 1980 Jan 1;19(3):705–708.
Published In
Inorganic Chemistry
DOI
EISSN
1520-510X
ISSN
0020-1669
Publication Date
January 1, 1980
Volume
19
Issue
3
Start / End Page
705 / 708
Related Subject Headings
- Inorganic & Nuclear Chemistry
- 0399 Other Chemical Sciences
- 0306 Physical Chemistry (incl. Structural)
- 0302 Inorganic Chemistry