A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II)
Publication
, Journal Article
Wertz, DW; Moseley, MA
Published in: Spectrochimica Acta Part A: Molecular Spectroscopy
January 1, 1980
Vibrational assignments of the complexes [RhClC7H8]2, PtCl2C7H8, and PdCl2C7H8 have been undertaken. A reinvestigation of the norbornadiene spectrum was necessary and a new set of assignments is given. The shift in energy of bands I and II and the out-of-plane olefinic CH wagging modes, as well as the relative energies of the bands associated with the metal-olefin motions are consistent with the total metal-norbornadiene interaction following the order Rh>Pt>Pd and the extent of the π component being ordered as Rh{reversed tilde equals}Pt>Pd. © 1980.
Duke Scholars
Published In
Spectrochimica Acta Part A: Molecular Spectroscopy
DOI
ISSN
0584-8539
Publication Date
January 1, 1980
Volume
36
Issue
5
Start / End Page
467 / 472
Citation
APA
Chicago
ICMJE
MLA
NLM
Wertz, D. W., & Moseley, M. A. (1980). A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II). Spectrochimica Acta Part A: Molecular Spectroscopy, 36(5), 467–472. https://doi.org/10.1016/0584-8539(80)80164-4
Wertz, D. W., and M. A. Moseley. “A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II).” Spectrochimica Acta Part A: Molecular Spectroscopy 36, no. 5 (January 1, 1980): 467–72. https://doi.org/10.1016/0584-8539(80)80164-4.
Wertz DW, Moseley MA. A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II). Spectrochimica Acta Part A: Molecular Spectroscopy. 1980 Jan 1;36(5):467–72.
Wertz, D. W., and M. A. Moseley. “A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II).” Spectrochimica Acta Part A: Molecular Spectroscopy, vol. 36, no. 5, Jan. 1980, pp. 467–72. Scopus, doi:10.1016/0584-8539(80)80164-4.
Wertz DW, Moseley MA. A vibrational study of the metal-olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II). Spectrochimica Acta Part A: Molecular Spectroscopy. 1980 Jan 1;36(5):467–472.
Published In
Spectrochimica Acta Part A: Molecular Spectroscopy
DOI
ISSN
0584-8539
Publication Date
January 1, 1980
Volume
36
Issue
5
Start / End Page
467 / 472