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Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy

Publication ,  Journal Article
Oas, TG; Griffin, RG; Levitt, MH
Published in: The Journal of Chemical Physics
January 1, 1988

A new resonance effect in solid-state nuclear magnetic resonance (NMR) is described. The effect involves a combination of magic-angle sample rotation with irradiation of a heteronuclear spin system at the Larmor frequency of one of the spin species. If the irradiation intensity is such as to establish a match between spin nutation and sample rotation, it is shown that the heteronuclear dipolar spin interaction is selectively reintroduced into the spectrum. This allows small dipolar coupling constants to be measured in the presence of large shielding anisotropies. Applications are anticipated for determination of internuclear distances in materials lacking long-range order, such as polycrystalline materials, polymers, and surfaces. © 1988 American Institute of Physics.

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Published In

The Journal of Chemical Physics

DOI

ISSN

0021-9606

Publication Date

January 1, 1988

Volume

89

Issue

2

Start / End Page

692 / 695

Related Subject Headings

  • Chemical Physics
  • 51 Physical sciences
  • 40 Engineering
  • 34 Chemical sciences
  • 09 Engineering
  • 03 Chemical Sciences
  • 02 Physical Sciences
 

Citation

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Oas, T. G., Griffin, R. G., & Levitt, M. H. (1988). Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy. The Journal of Chemical Physics, 89(2), 692–695. https://doi.org/10.1063/1.455191
Oas, T. G., R. G. Griffin, and M. H. Levitt. “Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy.” The Journal of Chemical Physics 89, no. 2 (January 1, 1988): 692–95. https://doi.org/10.1063/1.455191.
Oas TG, Griffin RG, Levitt MH. Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy. The Journal of Chemical Physics. 1988 Jan 1;89(2):692–5.
Oas, T. G., et al. “Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy.” The Journal of Chemical Physics, vol. 89, no. 2, Jan. 1988, pp. 692–95. Scopus, doi:10.1063/1.455191.
Oas TG, Griffin RG, Levitt MH. Rotary resonance recoupling of dipolar interactions in solid-state nuclear magnetic resonance spectroscopy. The Journal of Chemical Physics. 1988 Jan 1;89(2):692–695.

Published In

The Journal of Chemical Physics

DOI

ISSN

0021-9606

Publication Date

January 1, 1988

Volume

89

Issue

2

Start / End Page

692 / 695

Related Subject Headings

  • Chemical Physics
  • 51 Physical sciences
  • 40 Engineering
  • 34 Chemical sciences
  • 09 Engineering
  • 03 Chemical Sciences
  • 02 Physical Sciences