Formation of 1, 1, 1-trimethyl-N-sulfinylsilanamine from the direct reaction of sulfur dioxide with hexamethyldisilazane
Journal Article (Journal Article)
The direct, facilq reaction between sulfur dioxide and the common silylating agent hexamethyldisilazane (HMDS) resulting in the formation of 1, 1, 1-trimethyl-N-sulfinylsilanamine, (CH3)3 Si—N=S=0 (1), has not previously been reported, although sulfur dioxide is known to react with bis-(trimethylsilyl)diimine1 and Me3SiHgSiMe32 to form the unstable bis(trimethylsilyl) sulfoxylate (CH3)3 Si—O—S—O—Si(CH3)3 (2). Compound 1 was first made in 1966 from the reaction of tris(trimethylsilyl)amine with thionyl chloride at 70 °C in the presence of A1C13 catalyst.3 Since that time a number of other synthetic methods have also been reported for its formation.4-8 It should be noted that the germanium. © 1980, American Chemical Society. All rights reserved.
Full Text
Duke Authors
Cited Authors
- Davis, JF; Spicer, LD
Published Date
- January 1, 1980
Published In
Volume / Issue
- 19 / 7
Start / End Page
- 2191 - 2192
Electronic International Standard Serial Number (EISSN)
- 1520-510X
International Standard Serial Number (ISSN)
- 0020-1669
Digital Object Identifier (DOI)
- 10.1021/ic50209a078
Citation Source
- Scopus