Potentiometric determination of solvation numbers and hydration constants for cations


Journal Article

A technique is developed for determining solvation numbers and hydration constants for metal ions. Stability constants are obtained that are essentially independent of the solution composition for a wide range of solvents. It is shown that two ROH molecules can take part in hydronium(-like) complex formation. Solvation numbers are obtained for H+, OH-, and organic acid anions as well as for divalent metal ions and their monochelates.

Full Text

Duke Authors

Cited Authors

  • Van Uitert, CE; Spicer, LD; Van Uitert, LGG

Published Date

  • January 1, 1977

Published In

Volume / Issue

  • 81 / 1

Start / End Page

  • 40 - 47

International Standard Serial Number (ISSN)

  • 0022-3654

Digital Object Identifier (DOI)

  • 10.1021/j100516a010

Citation Source

  • Scopus