Instrumental methods and challenges in quantifying polybrominated diphenyl ethers in environmental extracts: a review.

Journal Article (Journal Article)

Increased interest in the fate, transport and toxicity of polybrominated diphenyl ethers (PBDEs) over the past few years has led to a variety of studies reporting different methods of analysis for these persistent organic pollutants. Because PBDEs encompass a range of vapor pressures, molecular weights and degrees of bromine substitution, various analytical methods can lead to discrimination of some PBDE congeners. Recent improvements in injection techniques and mass spectrometer ionization methods have led to a variety of options to determine PBDEs in environmental samples. The purpose of this paper is therefore to review the available literature describing the advantages and disadvantages in choosing an injection technique, gas chromatography column and detector. Additional discussion is given to the challenges in measuring PBDEs, including potential chromatographic interferences and the lack of commercial standards for higher brominated congeners, which provides difficulties in examining degradation and debromination of BDE congeners, particularly for BDE 209.

Full Text

Duke Authors

Cited Authors

  • Stapleton, HM

Published Date

  • October 2006

Published In

Volume / Issue

  • 386 / 4

Start / End Page

  • 807 - 817

PubMed ID

  • 17165211

Pubmed Central ID

  • PMC1764596

Electronic International Standard Serial Number (EISSN)

  • 1618-2650

International Standard Serial Number (ISSN)

  • 1618-2642

Digital Object Identifier (DOI)

  • 10.1007/s00216-006-0400-y


  • eng