Synthesis of the erythrina alkaloid 3-demethoxyerythratidinone. Novel acid-induced rearrangements of its precursors.
Journal Article (Journal Article)
[reaction: see text] A new strategy for the synthesis of 3-demethoxyerythratidinone has been developed and is based on an extraordinarily facile intramolecular Diels-Alder reaction of a 2-imido-substituted furan. During the course of the synthesis, several novel acid-induced rearrangement reactions were encountered.
Full Text
Duke Authors
Cited Authors
- Wang, Q; Padwa, A
Published Date
- February 2006
Published In
Volume / Issue
- 8 / 4
Start / End Page
- 601 - 604
PubMed ID
- 16468721
Pubmed Central ID
- PMC2495026
Electronic International Standard Serial Number (EISSN)
- 1523-7052
International Standard Serial Number (ISSN)
- 1523-7060
Digital Object Identifier (DOI)
- 10.1021/ol0527330
Language
- eng