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Synthesis and structure of dicationic, bis(gold) φ-alkene complexes containing a 2,2-bis(phosphino)biphenyl ligand

Publication ,  Journal Article
Brooner, REM; Widenhoefer, RA
Published in: Organometallics
January 23, 2012

The dicationic bis(gold)-biarylphosphine φ-alkene complexes {(PP)[Au(φ-alkene)]2}2+2SbF6 [PP = 2,2-bis(di-tertbutylphosphino) biphenyl; alkene = isobutylene, 1-pentene] were isolated in >95% yield from reaction of alkene with a 1:2 mixture of (PP)- (AuCl)2 and AgSbF6 and were characterized by NMR spectroscopy and X-ray crystallography. © 2012 American Chemical Society.

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Published In

Organometallics

DOI

EISSN

1520-6041

ISSN

0276-7333

Publication Date

January 23, 2012

Volume

31

Issue

2

Start / End Page

768 / 771

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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Brooner, R. E. M., & Widenhoefer, R. A. (2012). Synthesis and structure of dicationic, bis(gold) φ-alkene complexes containing a 2,2-bis(phosphino)biphenyl ligand. Organometallics, 31(2), 768–771. https://doi.org/10.1021/om200948z
Brooner, R. E. M., and R. A. Widenhoefer. “Synthesis and structure of dicationic, bis(gold) φ-alkene complexes containing a 2,2-bis(phosphino)biphenyl ligand.” Organometallics 31, no. 2 (January 23, 2012): 768–71. https://doi.org/10.1021/om200948z.
Brooner, R. E. M., and R. A. Widenhoefer. “Synthesis and structure of dicationic, bis(gold) φ-alkene complexes containing a 2,2-bis(phosphino)biphenyl ligand.” Organometallics, vol. 31, no. 2, Jan. 2012, pp. 768–71. Scopus, doi:10.1021/om200948z.
Journal cover image

Published In

Organometallics

DOI

EISSN

1520-6041

ISSN

0276-7333

Publication Date

January 23, 2012

Volume

31

Issue

2

Start / End Page

768 / 771

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry