Synthesis and structure of dicationic, bis(gold) φ-alkene complexes containing a 2,2-bis(phosphino)biphenyl ligand

Published

Journal Article

The dicationic bis(gold)-biarylphosphine φ-alkene complexes {(PP)[Au(φ-alkene)]2}2+2SbF6 [PP = 2,2-bis(di-tertbutylphosphino) biphenyl; alkene = isobutylene, 1-pentene] were isolated in >95% yield from reaction of alkene with a 1:2 mixture of (PP)- (AuCl)2 and AgSbF6 and were characterized by NMR spectroscopy and X-ray crystallography. © 2012 American Chemical Society.

Full Text

Duke Authors

Cited Authors

  • Brooner, REM; Widenhoefer, RA

Published Date

  • January 23, 2012

Published In

Volume / Issue

  • 31 / 2

Start / End Page

  • 768 - 771

Electronic International Standard Serial Number (EISSN)

  • 1520-6041

International Standard Serial Number (ISSN)

  • 0276-7333

Digital Object Identifier (DOI)

  • 10.1021/om200948z

Citation Source

  • Scopus