Platinum-catalyzed intramolecular asymmetric hydroarylation of unactivated alkenes with indoles.

Published

Journal Article

[reaction: see text] A 1:1 mixture of the platinum bis(phosphine) complex [(S)-4]PtCl2 [(S)-4 = (S)-3,5-t-Bu-4-MeO-MeOBIPHEP] catalyzes the intramolecular asymmetric hydroarylation of 2-(4-pentenyl)indoles in moderate to good yield with up to 90% ee.

Full Text

Duke Authors

Cited Authors

  • Han, X; Widenhoefer, RA

Published Date

  • August 2006

Published In

Volume / Issue

  • 8 / 17

Start / End Page

  • 3801 - 3804

PubMed ID

  • 16898821

Pubmed Central ID

  • 16898821

Electronic International Standard Serial Number (EISSN)

  • 1523-7052

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol061441b

Language

  • eng