Reaction of NO with Cp*3 Co3 (μ-H)4 preserves the tricobalt cluster and produces Cp*3 Co33 -NO)2

Journal Article

Cp*3Co3(μ-H)4 (4) reacts with NO to produce Cp*3Co3(μ3-NO)2 (3) which was characterized by X-ray crystallography. 3 is a diamagnetic 48 electron tricobalt cluster in which an equilateral triangular array of cobalt atoms (CoCoav=2.423(2) Å) is capped on each face by a μ3-NO ligand (Co-μ3-NOav=1.863(7) Å). © 1993.

Full Text

Duke Authors

Cited Authors

  • Casey, CP; Widenhoefer, RA; Hayashi, RK

Published Date

  • 1993

Published In

Volume / Issue

  • 212 / 1-2

Start / End Page

  • 81 - 85

International Standard Serial Number (ISSN)

  • 0020-1693

Digital Object Identifier (DOI)

  • 10.1016/S0020-1693(00)92312-0