Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )]
Publication
, Journal Article
Casey, CP; Widenhoefer, RA; Hallenbeck, SL; Gavney, JA
Published in: Journal of the Chemical Society, Chemical Communications
December 1, 1993
The reaction of [(C5Me5)3Co 3(μ-2-H)3(μ3-H)] 1 with 2 equiv. of CO forms the biscarbonyl dihydride cluster [(C5Me5) 3Co3(μ3-CO) (μ2-CO)(μ-H) 2] 2; tert-butyl isocyanide inserts into a Co-H bond of 1 to form the formimidoyl monohydride cluster [(C5Me5) 3Co3(μ-H)(μ3-η2-HC= NCMe3)] 5, via the intermediate [(C5Me5) 3Co3(μ3-CNCMe3) (μ2-CNCMe3)(μ-H)2] 6.
Duke Scholars
Published In
Journal of the Chemical Society, Chemical Communications
DOI
ISSN
0022-4936
Publication Date
December 1, 1993
Issue
22
Start / End Page
1692 / 1694
Citation
APA
Chicago
ICMJE
MLA
NLM
Casey, C. P., Widenhoefer, R. A., Hallenbeck, S. L., & Gavney, J. A. (1993). Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )]. Journal of the Chemical Society, Chemical Communications, (22), 1692–1694. https://doi.org/10.1039/C39930001692
Casey, C. P., R. A. Widenhoefer, S. L. Hallenbeck, and J. A. Gavney. “Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )].” Journal of the Chemical Society, Chemical Communications, no. 22 (December 1, 1993): 1692–94. https://doi.org/10.1039/C39930001692.
Casey CP, Widenhoefer RA, Hallenbeck SL, Gavney JA. Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )]. Journal of the Chemical Society, Chemical Communications. 1993 Dec 1;(22):1692–4.
Casey, C. P., et al. “Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )].” Journal of the Chemical Society, Chemical Communications, no. 22, Dec. 1993, pp. 1692–94. Scopus, doi:10.1039/C39930001692.
Casey CP, Widenhoefer RA, Hallenbeck SL, Gavney JA. Reaction of CO and tert-butyl isocyanide with the cluster [(C 5 Me5 )3 Co3 (μ2 -H) 3 (μ3 -H)] facile hydrogen transfer to isocyanide forms [(C5 Me5 )3 Co3 (μ-H) (μ3 -η2-HC=NCMe3 )]. Journal of the Chemical Society, Chemical Communications. 1993 Dec 1;(22):1692–1694.
Published In
Journal of the Chemical Society, Chemical Communications
DOI
ISSN
0022-4936
Publication Date
December 1, 1993
Issue
22
Start / End Page
1692 / 1694