Transition metal containing plasma polymers

Published

Journal Article

The plasma polymerization of the C2 hydrocarbons in the presence of Fe(CO)5vapor can lead to the formation of soluble cluster complexes (I) and/or high oxidation state iron both in the form of the oxide (II) and associated with the carboxylate or β-diketonate ion (III). Analysis of the electron spectroscopy for chemical analysis (ESCA) spectra obtained yields information regarding the nature of I on the one hand, and regarding the prevalence of II relative to III, on the other. The relative yield of I with respect to (II + III) can be controlled, at will, by variation of W/F. This permits control of the coating’s morphology (continuity) as shown by the electrodeposition of Prussian blue on smooth surfaces coated with plasma polymer containing I + II + III. © 1985, American Vacuum Society. All rights reserved.

Full Text

Duke Authors

Cited Authors

  • Morosoff, N; Hague, R; Clymer, SD; Crumbliss, AL

Published Date

  • January 1, 1985

Published In

Volume / Issue

  • 3 / 6

Start / End Page

  • 2098 - 2101

Electronic International Standard Serial Number (EISSN)

  • 1520-8559

International Standard Serial Number (ISSN)

  • 0734-2101

Digital Object Identifier (DOI)

  • 10.1116/1.572931

Citation Source

  • Scopus