Transition metal containing plasma polymers

Journal Article (Journal Article)

The plasma polymerization of the C hydrocarbons in the presence of Fe(CO) vapor can lead to the formation of soluble cluster complexes (I) and/or high oxidation state iron both in the form of the oxide (II) and associated with the carboxylate or β-diketonate ion (III). Analysis of the electron spectroscopy for chemical analysis (ESCA) spectra obtained yields information regarding the nature of I on the one hand, and regarding the prevalence of II relative to III, on the other. The relative yield of I with respect to (II + III) can be controlled, at will, by variation of W/F. This permits control of the coating’s morphology (continuity) as shown by the electrodeposition of Prussian blue on smooth surfaces coated with plasma polymer containing I + II + III. © 1985, American Vacuum Society. All rights reserved. 2 5

Full Text

Duke Authors

Cited Authors

  • Morosoff, N; Hague, R; Clymer, SD; Crumbliss, AL

Published Date

  • January 1, 1985

Published In

Volume / Issue

  • 3 / 6

Start / End Page

  • 2098 - 2101

Electronic International Standard Serial Number (EISSN)

  • 1520-8559

International Standard Serial Number (ISSN)

  • 0734-2101

Digital Object Identifier (DOI)

  • 10.1116/1.572931

Citation Source

  • Scopus