Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate

Journal Article (Journal Article)

These researchers provide experimental evidence which shows that the influence of thiolate ligation on the oxidizing ability of the high-valent oxo-iron intermediate likely comes from the ability of the thiolate ligand to stabilize an oxygen radical structure (Scheme 1; L = S ; species B). -

Duke Authors

Cited Authors

  • Urano, Y; Higuchi, T; Hirobe, M; Nagano, T

Published Date

  • May 1, 1998

Published In

Volume / Issue

  • 11 / 5

Start / End Page

  • 327 - 332

International Standard Serial Number (ISSN)

  • 1431-9268

Citation Source

  • Scopus