Molecular engineering of mechanophore activity for stress-responsive polymeric materials.
Publication
, Journal Article
Brown, CL; Craig, SL
Published in: Chemical science
April 2015
Force reactive functional groups, or mechanophores, have emerged as the basis of a potential strategy for sensing and countering stress-induced material failure. The general utility of this strategy is limited, however, because the levels of mechanophore activation in the bulk are typically low and observed only under large, typically irreversible strains. Strategies that enhance activation are therefore quite useful. Molecular-level design principles by which to engineer enhanced mechanophore activity are reviewed, with an emphasis on quantitative structure-activity studies determined for a family of gem-dihalocyclopropane mechanophores.
Duke Scholars
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Published In
Chemical science
DOI
EISSN
2041-6539
ISSN
2041-6520
Publication Date
April 2015
Volume
6
Issue
4
Start / End Page
2158 / 2165
Related Subject Headings
- 34 Chemical sciences
- 03 Chemical Sciences
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ICMJE
MLA
NLM
Brown, C. L., & Craig, S. L. (2015). Molecular engineering of mechanophore activity for stress-responsive polymeric materials. Chemical Science, 6(4), 2158–2165. https://doi.org/10.1039/c4sc01945h
Brown, Cameron L., and Stephen L. Craig. “Molecular engineering of mechanophore activity for stress-responsive polymeric materials.” Chemical Science 6, no. 4 (April 2015): 2158–65. https://doi.org/10.1039/c4sc01945h.
Brown CL, Craig SL. Molecular engineering of mechanophore activity for stress-responsive polymeric materials. Chemical science. 2015 Apr;6(4):2158–65.
Brown, Cameron L., and Stephen L. Craig. “Molecular engineering of mechanophore activity for stress-responsive polymeric materials.” Chemical Science, vol. 6, no. 4, Apr. 2015, pp. 2158–65. Epmc, doi:10.1039/c4sc01945h.
Brown CL, Craig SL. Molecular engineering of mechanophore activity for stress-responsive polymeric materials. Chemical science. 2015 Apr;6(4):2158–2165.
Published In
Chemical science
DOI
EISSN
2041-6539
ISSN
2041-6520
Publication Date
April 2015
Volume
6
Issue
4
Start / End Page
2158 / 2165
Related Subject Headings
- 34 Chemical sciences
- 03 Chemical Sciences