Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene.
Publication
, Journal Article
Kouznetsova, TB; Wang, J; Craig, SL
Published in: Chemphyschem : a European journal of chemical physics and physical chemistry
June 2017
Single-molecule force spectroscopy (SMFS) of multi-mechanophore polymers has been used to provide kinetic and mechanistic insights into mechanochemical reactions. Whereas biological systems have benefitted from force clamp spectroscopy, synthetic polymers have been studied primarily with constant-velocity methods. Here, force clamp SMFS is applied to the mechanically accelerated conrotatory ring opening of benzocyclobutene, and a comparison with constant-velocity SMFS extends the range of available rate-versus-force data and corroborates the use of constant-velocity SMFS to extract force dependencies.
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Published In
Chemphyschem : a European journal of chemical physics and physical chemistry
DOI
EISSN
1439-7641
ISSN
1439-4235
Publication Date
June 2017
Volume
18
Issue
11
Start / End Page
1486 / 1489
Related Subject Headings
- Chemical Physics
- 3406 Physical chemistry
- 3403 Macromolecular and materials chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
Citation
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Chicago
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Kouznetsova, T. B., Wang, J., & Craig, S. L. (2017). Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene. Chemphyschem : A European Journal of Chemical Physics and Physical Chemistry, 18(11), 1486–1489. https://doi.org/10.1002/cphc.201600463
Kouznetsova, Tatiana B., Junpeng Wang, and Stephen L. Craig. “Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene.” Chemphyschem : A European Journal of Chemical Physics and Physical Chemistry 18, no. 11 (June 2017): 1486–89. https://doi.org/10.1002/cphc.201600463.
Kouznetsova TB, Wang J, Craig SL. Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene. Chemphyschem : a European journal of chemical physics and physical chemistry. 2017 Jun;18(11):1486–9.
Kouznetsova, Tatiana B., et al. “Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene.” Chemphyschem : A European Journal of Chemical Physics and Physical Chemistry, vol. 18, no. 11, June 2017, pp. 1486–89. Epmc, doi:10.1002/cphc.201600463.
Kouznetsova TB, Wang J, Craig SL. Combined Constant-Force and Constant-Velocity Single-Molecule Force Spectroscopy of the Conrotatory Ring Opening Reaction of Benzocyclobutene. Chemphyschem : a European journal of chemical physics and physical chemistry. 2017 Jun;18(11):1486–1489.
Published In
Chemphyschem : a European journal of chemical physics and physical chemistry
DOI
EISSN
1439-7641
ISSN
1439-4235
Publication Date
June 2017
Volume
18
Issue
11
Start / End Page
1486 / 1489
Related Subject Headings
- Chemical Physics
- 3406 Physical chemistry
- 3403 Macromolecular and materials chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics