Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes.
Publication
, Journal Article
Ayer, SK; Roizen, JL
Published in: The Journal of organic chemistry
March 2019
Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions.
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Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2019
Volume
84
Issue
6
Start / End Page
3508 / 3523
Related Subject Headings
- Xanthine
- Sulfonic Acids
- Organic Chemistry
- Molecular Conformation
- Models, Molecular
- Esters
- Alkanes
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Ayer, S. K., & Roizen, J. L. (2019). Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes. The Journal of Organic Chemistry, 84(6), 3508–3523. https://doi.org/10.1021/acs.joc.9b00105
Ayer, Suraj K., and J. L. Roizen. “Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes.” The Journal of Organic Chemistry 84, no. 6 (March 2019): 3508–23. https://doi.org/10.1021/acs.joc.9b00105.
Ayer SK, Roizen JL. Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes. The Journal of organic chemistry. 2019 Mar;84(6):3508–23.
Ayer, Suraj K., and J. L. Roizen. “Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes.” The Journal of Organic Chemistry, vol. 84, no. 6, Mar. 2019, pp. 3508–23. Epmc, doi:10.1021/acs.joc.9b00105.
Ayer SK, Roizen JL. Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes. The Journal of organic chemistry. 2019 Mar;84(6):3508–3523.
Published In
The Journal of organic chemistry
DOI
EISSN
1520-6904
ISSN
0022-3263
Publication Date
March 2019
Volume
84
Issue
6
Start / End Page
3508 / 3523
Related Subject Headings
- Xanthine
- Sulfonic Acids
- Organic Chemistry
- Molecular Conformation
- Models, Molecular
- Esters
- Alkanes
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 0305 Organic Chemistry