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Retrocyclopropanation reactions of fullerenes: complete product analyses.

Publication ,  Journal Article
Herranz, MA; Cox, CT; Echegoyen, L
Published in: The Journal of organic chemistry
June 2003

Mono- and bis-pyrene malonates 1 and 2 were synthesized and reacted with C(60) to prepare the corresponding Bingel adducts 3 and 4. These compounds were characterized electrochemically and exhibited the well-established retrocyclopropanation reaction when subjected to bulk electrolytic reductions. For the first time, it was possible to perform detailed product analyses after the retrocyclopropanation reactions, and these showed the presence of the original malonates 1 and 2 along with C(60), in reasonable yields, around 50%.

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Published In

The Journal of organic chemistry

DOI

EISSN

1520-6904

ISSN

0022-3263

Publication Date

June 2003

Volume

68

Issue

12

Start / End Page

5009 / 5012

Related Subject Headings

  • Organic Chemistry
  • 3405 Organic chemistry
  • 3404 Medicinal and biomolecular chemistry
  • 0305 Organic Chemistry
  • 0304 Medicinal and Biomolecular Chemistry
 

Citation

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Herranz, M. A., Cox, C. T., & Echegoyen, L. (2003). Retrocyclopropanation reactions of fullerenes: complete product analyses. The Journal of Organic Chemistry, 68(12), 5009–5012. https://doi.org/10.1021/jo034102u
Herranz, M Angeles, Charles T. Cox, and Luis Echegoyen. “Retrocyclopropanation reactions of fullerenes: complete product analyses.The Journal of Organic Chemistry 68, no. 12 (June 2003): 5009–12. https://doi.org/10.1021/jo034102u.
Herranz MA, Cox CT, Echegoyen L. Retrocyclopropanation reactions of fullerenes: complete product analyses. The Journal of organic chemistry. 2003 Jun;68(12):5009–12.
Herranz, M. Angeles, et al. “Retrocyclopropanation reactions of fullerenes: complete product analyses.The Journal of Organic Chemistry, vol. 68, no. 12, June 2003, pp. 5009–12. Epmc, doi:10.1021/jo034102u.
Herranz MA, Cox CT, Echegoyen L. Retrocyclopropanation reactions of fullerenes: complete product analyses. The Journal of organic chemistry. 2003 Jun;68(12):5009–5012.
Journal cover image

Published In

The Journal of organic chemistry

DOI

EISSN

1520-6904

ISSN

0022-3263

Publication Date

June 2003

Volume

68

Issue

12

Start / End Page

5009 / 5012

Related Subject Headings

  • Organic Chemistry
  • 3405 Organic chemistry
  • 3404 Medicinal and biomolecular chemistry
  • 0305 Organic Chemistry
  • 0304 Medicinal and Biomolecular Chemistry