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The Natural Optical Activity of Tris(Ethylenediamine)Metal(II) Nitrates V. The Single Crystal Circular Dichroism Spectrum of Ni(en)3 (NO3 )2

Publication ,  Journal Article
Yang, MC; Palmer, RA
Published in: Journal of the Chinese Chemical Society
January 1, 1978

The axial CD spectra of single crystal of Zn(en)3(NO3)2 doped with 1‐50% Ni(en)3(NO3)2 have been observed at temperatures from ambient to 5 K. The increase in R of the 3E[3T3g(F)] transition as the temperature decreases is consistent with the magnetic dipole allowed character of the parent octahedral transition. The electric and magnetic dipole forbidden transition to the 3T1g(F) octahedral level gives rise to a relatively weak axial CD band with an unusual temperature dependent splitting. This structure is attributed to electric quadrupole intensity, which is allowed for transitions to both the E and 3A2[3T1g(F)] levels in D3 symmetry. Copyright © 1978 The Chemical Society Located in Taipei & Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim, Germany

Duke Scholars

Published In

Journal of the Chinese Chemical Society

DOI

EISSN

2192-6549

ISSN

0009-4536

Publication Date

January 1, 1978

Volume

25

Issue

4

Start / End Page

195 / 201

Related Subject Headings

  • General Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences
 

Citation

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Yang, M. C., & Palmer, R. A. (1978). The Natural Optical Activity of Tris(Ethylenediamine)Metal(II) Nitrates V. The Single Crystal Circular Dichroism Spectrum of Ni(en)3 (NO3 )2. Journal of the Chinese Chemical Society, 25(4), 195–201. https://doi.org/10.1002/jccs.197800032
Yang, M. C., and R. A. Palmer. “The Natural Optical Activity of Tris(Ethylenediamine)Metal(II) Nitrates V. The Single Crystal Circular Dichroism Spectrum of Ni(en)3 (NO3 )2.” Journal of the Chinese Chemical Society 25, no. 4 (January 1, 1978): 195–201. https://doi.org/10.1002/jccs.197800032.
Yang, M. C., and R. A. Palmer. “The Natural Optical Activity of Tris(Ethylenediamine)Metal(II) Nitrates V. The Single Crystal Circular Dichroism Spectrum of Ni(en)3 (NO3 )2.” Journal of the Chinese Chemical Society, vol. 25, no. 4, Jan. 1978, pp. 195–201. Scopus, doi:10.1002/jccs.197800032.
Journal cover image

Published In

Journal of the Chinese Chemical Society

DOI

EISSN

2192-6549

ISSN

0009-4536

Publication Date

January 1, 1978

Volume

25

Issue

4

Start / End Page

195 / 201

Related Subject Headings

  • General Chemistry
  • 34 Chemical sciences
  • 03 Chemical Sciences