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Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes

Publication ,  Journal Article
Widenhoefer, RA; Vadehra, A; Cheruvu, PK
Published in: Organometallics
October 25, 1999

A 1:1 mixture of the palladium phenanthroline complex (phen)Pd(Me)Cl and NaBAr4 (phen = 1,10-phenanthroline; Ar = 3,5-C6H3(CF3)2) catalyzed the reaction of 4,4-disubstituted 1,6-dienes with trialkylgermanes at 80°C in 1,2-dichloroethane (DCE) to form R3GeCH2-substituted cyclopentanes in good yield with high trans selectivity.

Duke Scholars

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

October 25, 1999

Volume

18

Issue

22

Start / End Page

4614 / 4618

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry
 

Citation

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MLA
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Widenhoefer, R. A., Vadehra, A., & Cheruvu, P. K. (1999). Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes. Organometallics, 18(22), 4614–4618. https://doi.org/10.1021/om990546y
Widenhoefer, R. A., A. Vadehra, and P. K. Cheruvu. “Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes.” Organometallics 18, no. 22 (October 25, 1999): 4614–18. https://doi.org/10.1021/om990546y.
Widenhoefer RA, Vadehra A, Cheruvu PK. Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes. Organometallics. 1999 Oct 25;18(22):4614–8.
Widenhoefer, R. A., et al. “Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes.” Organometallics, vol. 18, no. 22, Oct. 1999, pp. 4614–18. Scopus, doi:10.1021/om990546y.
Widenhoefer RA, Vadehra A, Cheruvu PK. Cyclization/Hydrogermylation of Functionalized 1,6-Dienes Catalyzed by Cationic Palladium Complexes. Organometallics. 1999 Oct 25;18(22):4614–4618.
Journal cover image

Published In

Organometallics

DOI

ISSN

0276-7333

Publication Date

October 25, 1999

Volume

18

Issue

22

Start / End Page

4614 / 4618

Related Subject Headings

  • Organic Chemistry
  • 3406 Physical chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0305 Organic Chemistry
  • 0302 Inorganic Chemistry