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Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, μ4-ethylenethiourea-cyclo- tetrakis-μ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate

Publication ,  Journal Article
Crumbliss, AL; Gestaut, LJ; Rickard, RC; McPhail, AT
Published in: Journal of the Chemical Society, Chemical Communications
January 1, 1974

The structure, geometry, and bonding in [Cu4(C3H 6N2S)9(NO3)4],6H 2O have been established by X-ray analysis which reveals discrete Cu4(C3H6N2S)94+ cations containing an alternating Cu-S eight-membered ring with a unique ethylenethiourea ligand in an axial position bridging four copper atoms.

Duke Scholars

Published In

Journal of the Chemical Society, Chemical Communications

DOI

ISSN

0022-4936

Publication Date

January 1, 1974

Issue

14

Start / End Page

545 / 546
 

Citation

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Crumbliss, A. L., Gestaut, L. J., Rickard, R. C., & McPhail, A. T. (1974). Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, μ4-ethylenethiourea-cyclo- tetrakis-μ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate. Journal of the Chemical Society, Chemical Communications, (14), 545–546. https://doi.org/10.1039/C39740000545
Crumbliss, A. L., L. J. Gestaut, R. C. Rickard, and A. T. McPhail. “Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, μ4-ethylenethiourea-cyclo- tetrakis-μ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate.” Journal of the Chemical Society, Chemical Communications, no. 14 (January 1, 1974): 545–46. https://doi.org/10.1039/C39740000545.
Crumbliss, A. L., et al. “Preparation and X-ray crystal structure of a novel tetranuclear copper(I) ethylenethiourea cluster complex, μ4-ethylenethiourea-cyclo- tetrakis-μ-(ethylenethiourea)tetrakis[ethylenethioureacopper(I)] nitrate hexahydrate.” Journal of the Chemical Society, Chemical Communications, no. 14, Jan. 1974, pp. 545–46. Scopus, doi:10.1039/C39740000545.

Published In

Journal of the Chemical Society, Chemical Communications

DOI

ISSN

0022-4936

Publication Date

January 1, 1974

Issue

14

Start / End Page

545 / 546