Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission
Publication
, Journal Article
Saksena, AK; McPhail, AT; Onan, KD
Published in: Tetrahedron Letters
January 1, 1981
Treatment of hydroxymethylene ketone 6 with trimethylene dithiotosylate according to literature conditions,3b led to the novel CC ring scission product 7 in high yield; also, the hydroxide-initiated cleavage4 of 1 gave the β-elimination product 13 which underwent a highly stereospecific addition of diazomethane to provide 15. © 1981.
Duke Scholars
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
January 1, 1981
Volume
22
Issue
22
Start / End Page
2067 / 2070
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry
Citation
APA
Chicago
ICMJE
MLA
NLM
Saksena, A. K., McPhail, A. T., & Onan, K. D. (1981). Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission. Tetrahedron Letters, 22(22), 2067–2070. https://doi.org/10.1016/S0040-4039(01)93278-2
Saksena, A. K., A. T. McPhail, and K. D. Onan. “Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission.” Tetrahedron Letters 22, no. 22 (January 1, 1981): 2067–70. https://doi.org/10.1016/S0040-4039(01)93278-2.
Saksena AK, McPhail AT, Onan KD. Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission. Tetrahedron Letters. 1981 Jan 1;22(22):2067–70.
Saksena, A. K., et al. “Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission.” Tetrahedron Letters, vol. 22, no. 22, Jan. 1981, pp. 2067–70. Scopus, doi:10.1016/S0040-4039(01)93278-2.
Saksena AK, McPhail AT, Onan KD. Carbocyclic analogs of C-nucleosides: a key intermediate via a novel and efficient CC ring scission. Tetrahedron Letters. 1981 Jan 1;22(22):2067–2070.
Published In
Tetrahedron Letters
DOI
ISSN
0040-4039
Publication Date
January 1, 1981
Volume
22
Issue
22
Start / End Page
2067 / 2070
Related Subject Headings
- Organic Chemistry
- 3405 Organic chemistry
- 3404 Medicinal and biomolecular chemistry
- 3101 Biochemistry and cell biology
- 0305 Organic Chemistry
- 0304 Medicinal and Biomolecular Chemistry