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Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions

Publication ,  Journal Article
Porter, NA; Wu, WX; McPhail, AT
Published in: Tetrahedron Letters
February 4, 1991

Competition rate constants were determined for the addition of cyclohexyl radical to α,β unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state. © 1991.

Duke Scholars

Published In

Tetrahedron Letters

DOI

ISSN

0040-4039

Publication Date

February 4, 1991

Volume

32

Issue

6

Start / End Page

707 / 710

Related Subject Headings

  • Organic Chemistry
  • 3405 Organic chemistry
  • 3404 Medicinal and biomolecular chemistry
  • 3101 Biochemistry and cell biology
  • 0305 Organic Chemistry
  • 0304 Medicinal and Biomolecular Chemistry
 

Citation

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Porter, N. A., Wu, W. X., & McPhail, A. T. (1991). Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions. Tetrahedron Letters, 32(6), 707–710. https://doi.org/10.1016/S0040-4039(00)74863-5
Porter, N. A., W. X. Wu, and A. T. McPhail. “Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions.” Tetrahedron Letters 32, no. 6 (February 4, 1991): 707–10. https://doi.org/10.1016/S0040-4039(00)74863-5.
Porter, N. A., et al. “Competition rate constants for addition of cyclohexyl radical to amide substituted alkenes: origins of acyclic stereoselection in radical additions.” Tetrahedron Letters, vol. 32, no. 6, Feb. 1991, pp. 707–10. Scopus, doi:10.1016/S0040-4039(00)74863-5.
Journal cover image

Published In

Tetrahedron Letters

DOI

ISSN

0040-4039

Publication Date

February 4, 1991

Volume

32

Issue

6

Start / End Page

707 / 710

Related Subject Headings

  • Organic Chemistry
  • 3405 Organic chemistry
  • 3404 Medicinal and biomolecular chemistry
  • 3101 Biochemistry and cell biology
  • 0305 Organic Chemistry
  • 0304 Medicinal and Biomolecular Chemistry