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Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine

Publication ,  Journal Article
Farlow, B; Nile, TA; Walsh, JL; McPhail, AT
Published in: Polyhedron
January 1, 1993

4′-Ferrocenyl-2,2′:6′,2″-terpyridine(Fctrpy) has been prepared from ferrocene carboxaldehyde and 2-acetylpyridine. A single crystal X-ray structure analysis indicates typical bond distances and angles with nearly coplanar aromatic rings. The angle between the cyclopentadienyl ring of the ferrocene moiety and the central pyridyl ring of the terpyridine is 19.2° Ruthenium complexes, Ru(Fctrpy)22+ and Ru(trpy) (Fctrpy)2+ (trpy = 2,2′:6′,2″-terpyridine) have been prepared and characterized electrochemically and spectrophotometrically. © 1993.

Duke Scholars

Published In

Polyhedron

DOI

ISSN

0277-5387

Publication Date

January 1, 1993

Volume

12

Issue

23

Start / End Page

2891 / 2894

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry
 

Citation

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ICMJE
MLA
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Farlow, B., Nile, T. A., Walsh, J. L., & McPhail, A. T. (1993). Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine. Polyhedron, 12(23), 2891–2894. https://doi.org/10.1016/S0277-5387(00)80074-1
Farlow, B., T. A. Nile, J. L. Walsh, and A. T. McPhail. “Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine.” Polyhedron 12, no. 23 (January 1, 1993): 2891–94. https://doi.org/10.1016/S0277-5387(00)80074-1.
Farlow B, Nile TA, Walsh JL, McPhail AT. Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine. Polyhedron. 1993 Jan 1;12(23):2891–4.
Farlow, B., et al. “Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine.” Polyhedron, vol. 12, no. 23, Jan. 1993, pp. 2891–94. Scopus, doi:10.1016/S0277-5387(00)80074-1.
Farlow B, Nile TA, Walsh JL, McPhail AT. Synthesis, x-ray structural determination and coordination chemistry of 4′-ferrocenyl-2,2′:6′,2″-terpyridine. Polyhedron. 1993 Jan 1;12(23):2891–2894.
Journal cover image

Published In

Polyhedron

DOI

ISSN

0277-5387

Publication Date

January 1, 1993

Volume

12

Issue

23

Start / End Page

2891 / 2894

Related Subject Headings

  • Inorganic & Nuclear Chemistry
  • 3403 Macromolecular and materials chemistry
  • 3402 Inorganic chemistry
  • 0399 Other Chemical Sciences
  • 0306 Physical Chemistry (incl. Structural)
  • 0302 Inorganic Chemistry