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Three-state model for two-electron transfer reactions

Publication ,  Journal Article
Zusman, LD; Beratan, DN
Published in: Journal of Physical Chemistry A
May 29, 1997

Much of electron transfer based catalysis relies upon multielectron rather than single-electron transfer processes. If the multielectron events proceed through stable one-electron intermediates, conventional theory describes the events However, when an unstable one-electron intermediate plays a role, when a stable intermediate lives for a brief period of time, or when concerted multielectron events occur, the electronic coupling and free energy dependence of the rate is distinct from that arising in one-electron theories. We describe several new features that can arise in multielectron processes, predict their experimental signature, and show how these ideas can be applied to specific experimental systems.

Duke Scholars

Published In

Journal of Physical Chemistry A

DOI

ISSN

1089-5639

Publication Date

May 29, 1997

Volume

101

Issue

22

Start / End Page

4136 / 4141

Related Subject Headings

  • 5102 Atomic, molecular and optical physics
  • 3407 Theoretical and computational chemistry
  • 3406 Physical chemistry
  • 0307 Theoretical and Computational Chemistry
  • 0306 Physical Chemistry (incl. Structural)
  • 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
 

Citation

APA
Chicago
ICMJE
MLA
NLM
Zusman, L. D., & Beratan, D. N. (1997). Three-state model for two-electron transfer reactions. Journal of Physical Chemistry A, 101(22), 4136–4141. https://doi.org/10.1021/jp970123e
Zusman, L. D., and D. N. Beratan. “Three-state model for two-electron transfer reactions.” Journal of Physical Chemistry A 101, no. 22 (May 29, 1997): 4136–41. https://doi.org/10.1021/jp970123e.
Zusman LD, Beratan DN. Three-state model for two-electron transfer reactions. Journal of Physical Chemistry A. 1997 May 29;101(22):4136–41.
Zusman, L. D., and D. N. Beratan. “Three-state model for two-electron transfer reactions.” Journal of Physical Chemistry A, vol. 101, no. 22, May 1997, pp. 4136–41. Scopus, doi:10.1021/jp970123e.
Zusman LD, Beratan DN. Three-state model for two-electron transfer reactions. Journal of Physical Chemistry A. 1997 May 29;101(22):4136–4141.
Journal cover image

Published In

Journal of Physical Chemistry A

DOI

ISSN

1089-5639

Publication Date

May 29, 1997

Volume

101

Issue

22

Start / End Page

4136 / 4141

Related Subject Headings

  • 5102 Atomic, molecular and optical physics
  • 3407 Theoretical and computational chemistry
  • 3406 Physical chemistry
  • 0307 Theoretical and Computational Chemistry
  • 0306 Physical Chemistry (incl. Structural)
  • 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics