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Practical synthesis of fully protected globotriaose and its glycopolymers

Publication ,  Journal Article
Matsuoka, K; Goshu, Y; Takezawa, Y; Mori, T; Sakamoto, JI; Yamada, A; Onaga, T; Koyama, T; Hatano, K; Snyder, PW; Toone, EJ; Terunuma, D
Published in: Carbohydrate Polymers
June 1, 2007

Convenient and useful construction of a trisaccharide moiety of globotriaosyl ceramide was performed by means of modified Ogawa's protocol. In order to evaluate an efficiency of new class of glycopolymers, further chemical transformations of the trisaccharide were accomplished to afford a globotriaosyl carbohydrate monomer, and homopolymerization of the monomer by a general radical polymerization protocol gave a high-density glycopolymer in 84.3% yield after usual work-up procedures. In addition to the homopolymer, a copolymer composed of carbohydrate units and acrylamide units was also synthesized by the radical polymerization in 96.7% yield. © 2006 Elsevier Ltd. All rights reserved.

Duke Scholars

Published In

Carbohydrate Polymers

DOI

ISSN

0144-8617

Publication Date

June 1, 2007

Volume

69

Issue

2

Start / End Page

326 / 335

Related Subject Headings

  • Polymers
  • 4004 Chemical engineering
  • 3101 Biochemistry and cell biology
  • 3006 Food sciences
  • 0908 Food Sciences
  • 0305 Organic Chemistry
  • 0303 Macromolecular and Materials Chemistry
 

Citation

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Matsuoka, K., Goshu, Y., Takezawa, Y., Mori, T., Sakamoto, J. I., Yamada, A., … Terunuma, D. (2007). Practical synthesis of fully protected globotriaose and its glycopolymers. Carbohydrate Polymers, 69(2), 326–335. https://doi.org/10.1016/j.carbpol.2006.10.011
Matsuoka, K., Y. Goshu, Y. Takezawa, T. Mori, J. I. Sakamoto, A. Yamada, T. Onaga, et al. “Practical synthesis of fully protected globotriaose and its glycopolymers.” Carbohydrate Polymers 69, no. 2 (June 1, 2007): 326–35. https://doi.org/10.1016/j.carbpol.2006.10.011.
Matsuoka K, Goshu Y, Takezawa Y, Mori T, Sakamoto JI, Yamada A, et al. Practical synthesis of fully protected globotriaose and its glycopolymers. Carbohydrate Polymers. 2007 Jun 1;69(2):326–35.
Matsuoka, K., et al. “Practical synthesis of fully protected globotriaose and its glycopolymers.” Carbohydrate Polymers, vol. 69, no. 2, June 2007, pp. 326–35. Scopus, doi:10.1016/j.carbpol.2006.10.011.
Matsuoka K, Goshu Y, Takezawa Y, Mori T, Sakamoto JI, Yamada A, Onaga T, Koyama T, Hatano K, Snyder PW, Toone EJ, Terunuma D. Practical synthesis of fully protected globotriaose and its glycopolymers. Carbohydrate Polymers. 2007 Jun 1;69(2):326–335.
Journal cover image

Published In

Carbohydrate Polymers

DOI

ISSN

0144-8617

Publication Date

June 1, 2007

Volume

69

Issue

2

Start / End Page

326 / 335

Related Subject Headings

  • Polymers
  • 4004 Chemical engineering
  • 3101 Biochemistry and cell biology
  • 3006 Food sciences
  • 0908 Food Sciences
  • 0305 Organic Chemistry
  • 0303 Macromolecular and Materials Chemistry