Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon.
Publication
, Journal Article
Kang, YK; Deria, P; Carroll, PJ; Therien, MJ
Published in: Organic letters
April 2008
We report the synthesis, structure, and characterization of a novel ethyne synthon, 1,2-bis(4',4',5',5'-tetramethyl[1',3',2']dioxaborolan-2'-yl)ethyne (B2C2). We demonstrate the utility of B2C2 in the Suzuki-Miyaura polycondensation reaction, synthesizing a water-soluble poly(p-phenyleneethynylene) from [2,5-diiodo-1,4-bis(3-propoxy-sulfonicacid)benzene] sodium salt in neat water under an aerobic atmosphere.
Duke Scholars
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
April 2008
Volume
10
Issue
7
Start / End Page
1341 / 1344
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Kang, Y. K., Deria, P., Carroll, P. J., & Therien, M. J. (2008). Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon. Organic Letters, 10(7), 1341–1344. https://doi.org/10.1021/ol702758f
Kang, Youn K., Pravas Deria, Patrick J. Carroll, and Michael J. Therien. “Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon.” Organic Letters 10, no. 7 (April 2008): 1341–44. https://doi.org/10.1021/ol702758f.
Kang YK, Deria P, Carroll PJ, Therien MJ. Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon. Organic letters. 2008 Apr;10(7):1341–4.
Kang, Youn K., et al. “Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon.” Organic Letters, vol. 10, no. 7, Apr. 2008, pp. 1341–44. Epmc, doi:10.1021/ol702758f.
Kang YK, Deria P, Carroll PJ, Therien MJ. Synthesis of water-soluble poly(p-phenyleneethynylene) in neat water under aerobic conditions via Suzuki-Miyaura polycondensation using a diborylethyne synthon. Organic letters. 2008 Apr;10(7):1341–1344.
Published In
Organic letters
DOI
EISSN
1523-7052
ISSN
1523-7060
Publication Date
April 2008
Volume
10
Issue
7
Start / End Page
1341 / 1344
Related Subject Headings
- Organic Chemistry
- 34 Chemical sciences
- 03 Chemical Sciences