Reactive cross-talk between adjacent tension-trapped transition states.
Publication
, Journal Article
Lenhardt, JM; Ogle, JW; Ong, MT; Choe, R; Martinez, TJ; Craig, SL
Published in: Journal of the American Chemical Society
March 2011
Tension along a polymer chain traps neighboring s-trans/s-trans-1,3-diradicals from the mechanically induced ring opening of gem-difluorocyclopropanes (gDFCs). The diradicals correspond to the transition states of the force-free thermal isomerization reactions of gDFCs, and the tension trapping allows a new disproportionation reaction between two simultaneously trapped diradicals to take place.
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Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
March 2011
Volume
133
Issue
10
Start / End Page
3222 / 3225
Related Subject Headings
- Polymers
- Isomerism
- Hot Temperature
- General Chemistry
- Cyclopropanes
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
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MLA
NLM
Lenhardt, J. M., Ogle, J. W., Ong, M. T., Choe, R., Martinez, T. J., & Craig, S. L. (2011). Reactive cross-talk between adjacent tension-trapped transition states. Journal of the American Chemical Society, 133(10), 3222–3225. https://doi.org/10.1021/ja107645c
Lenhardt, Jeremy M., James W. Ogle, Mitchell T. Ong, Robert Choe, Todd J. Martinez, and Stephen L. Craig. “Reactive cross-talk between adjacent tension-trapped transition states.” Journal of the American Chemical Society 133, no. 10 (March 2011): 3222–25. https://doi.org/10.1021/ja107645c.
Lenhardt JM, Ogle JW, Ong MT, Choe R, Martinez TJ, Craig SL. Reactive cross-talk between adjacent tension-trapped transition states. Journal of the American Chemical Society. 2011 Mar;133(10):3222–5.
Lenhardt, Jeremy M., et al. “Reactive cross-talk between adjacent tension-trapped transition states.” Journal of the American Chemical Society, vol. 133, no. 10, Mar. 2011, pp. 3222–25. Epmc, doi:10.1021/ja107645c.
Lenhardt JM, Ogle JW, Ong MT, Choe R, Martinez TJ, Craig SL. Reactive cross-talk between adjacent tension-trapped transition states. Journal of the American Chemical Society. 2011 Mar;133(10):3222–3225.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
March 2011
Volume
133
Issue
10
Start / End Page
3222 / 3225
Related Subject Headings
- Polymers
- Isomerism
- Hot Temperature
- General Chemistry
- Cyclopropanes
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences