Intramolecular microsolvation of S(N)2 transition states
Publication
, Journal Article
Craig, SL; Brauman, JI
Published in: Journal of the American Chemical Society
July 21, 1999
Introduction of an ω-substituent (CN, Cl, or OH) onto a primary n- alkyl chloride significantly enhances the rate of S(N)2 chloride exchange in the gas phase. Trends in reactivity suggest that the rate acceleration depends primarily on through-space solvation of the transition state, especially charge-dipole interactions. The potential energy surfaces and dynamics of these reactions are discussed.
Duke Scholars
Published In
Journal of the American Chemical Society
DOI
ISSN
0002-7863
Publication Date
July 21, 1999
Volume
121
Issue
28
Start / End Page
6690 / 6699
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Craig, S. L., & Brauman, J. I. (1999). Intramolecular microsolvation of S(N)2 transition states. Journal of the American Chemical Society, 121(28), 6690–6699. https://doi.org/10.1021/ja983010x
Craig, S. L., and J. I. Brauman. “Intramolecular microsolvation of S(N)2 transition states.” Journal of the American Chemical Society 121, no. 28 (July 21, 1999): 6690–99. https://doi.org/10.1021/ja983010x.
Craig SL, Brauman JI. Intramolecular microsolvation of S(N)2 transition states. Journal of the American Chemical Society. 1999 Jul 21;121(28):6690–9.
Craig, S. L., and J. I. Brauman. “Intramolecular microsolvation of S(N)2 transition states.” Journal of the American Chemical Society, vol. 121, no. 28, July 1999, pp. 6690–99. Scopus, doi:10.1021/ja983010x.
Craig SL, Brauman JI. Intramolecular microsolvation of S(N)2 transition states. Journal of the American Chemical Society. 1999 Jul 21;121(28):6690–6699.
Published In
Journal of the American Chemical Society
DOI
ISSN
0002-7863
Publication Date
July 21, 1999
Volume
121
Issue
28
Start / End Page
6690 / 6699
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences