Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions
Publication
, Journal Article
Dhungana, S; Crumbliss, AL
Published in: Chemtracts
January 1, 2001
The hexaaquaions of Rh(III) and Ru(II) seem to undergo water exchange via disparate mechanisms in spite of being isoelectronic in nature. The possibility for a t2g6 ion to undergo ligand substitution reaction via an Ia mechanism definitely complicates simple rules for mechanistic interpretation and supports critics who disfavor broad application of δV≠ data to mechanistic interpretation.
Duke Scholars
Published In
Chemtracts
ISSN
1431-9268
Publication Date
January 1, 2001
Volume
14
Issue
1
Start / End Page
42 / 47
Related Subject Headings
- Organic Chemistry
Citation
APA
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ICMJE
MLA
NLM
Dhungana, S., & Crumbliss, A. L. (2001). Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions. Chemtracts, 14(1), 42–47.
Dhungana, S., and A. L. Crumbliss. “Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions.” Chemtracts 14, no. 1 (January 1, 2001): 42–47.
Dhungana S, Crumbliss AL. Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions. Chemtracts. 2001 Jan 1;14(1):42–7.
Dhungana, S., and A. L. Crumbliss. “Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions.” Chemtracts, vol. 14, no. 1, Jan. 2001, pp. 42–47.
Dhungana S, Crumbliss AL. Can octahedral t2g 6 complexes substitute associatively? The case of the isoelectronic Ruthenium(II) and Rhodium(III) hexaaquaions. Chemtracts. 2001 Jan 1;14(1):42–47.
Published In
Chemtracts
ISSN
1431-9268
Publication Date
January 1, 2001
Volume
14
Issue
1
Start / End Page
42 / 47
Related Subject Headings
- Organic Chemistry