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Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines

Publication ,  Journal Article
Flaherty, M; Crumbliss, AL
Published in: Chemtracts
August 6, 2001

The researchers have successfully demonstrated that by generating a change in the redox state of the central metal ion, in a conformationally biased complex, they are able to effect a change in the ligand-binding mode. This change in the first coordination sphere then forces a subsequent change in the second coordination shell. By carefully choosing ligands that contain a chiral center, the researchers were able to monitor the change in the second coordination shell by spectroscopically observing a shift in the chirality of the molecule.

Duke Scholars

Published In

Chemtracts

ISSN

1431-9268

Publication Date

August 6, 2001

Volume

14

Issue

5

Start / End Page

237 / 242

Related Subject Headings

  • Organic Chemistry
 

Citation

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MLA
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Flaherty, M., & Crumbliss, A. L. (2001). Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines. Chemtracts, 14(5), 237–242.
Flaherty, M., and A. L. Crumbliss. “Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines.” Chemtracts 14, no. 5 (August 6, 2001): 237–42.
Flaherty M, Crumbliss AL. Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines. Chemtracts. 2001 Aug 6;14(5):237–42.
Flaherty, M., and A. L. Crumbliss. “Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines.” Chemtracts, vol. 14, no. 5, Aug. 2001, pp. 237–42.
Flaherty M, Crumbliss AL. Electron-induced inversion of helical chirality in copper complexes of N,N-dialkylmethionines. Chemtracts. 2001 Aug 6;14(5):237–242.

Published In

Chemtracts

ISSN

1431-9268

Publication Date

August 6, 2001

Volume

14

Issue

5

Start / End Page

237 / 242

Related Subject Headings

  • Organic Chemistry