From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies.
Publication
, Journal Article
Godeau, G; Navailles, L; Nallet, F; Lin, X; McIntosh, TJ; Grinstaff, MW
Published in: Macromolecules
March 13, 2012
A polystyrenylphosphonium polymer was synthesized and complexed with various carboxylic acid derivatives to form new solid-state polyelectrolyte-surfactant assemblies. The properties of these ionic materials were highly dependent on the nature of the anion and included a brittle material, a rubbery ball that bounces, or a sticky fiber. The values for the equilibrium modulus, storage modulus, and loss modulus were dependent on the composition of the carboxylic acid and the number of electrostatic interactions. Small-angle X-ray scattering studies on the supramolecular assemblies confirmed a bilayer structure for two of the assemblies.
Duke Scholars
Published In
Macromolecules
DOI
ISSN
0024-9297
Publication Date
March 13, 2012
Volume
45
Issue
5
Start / End Page
2509 / 2513
Location
United States
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Godeau, G., Navailles, L., Nallet, F., Lin, X., McIntosh, T. J., & Grinstaff, M. W. (2012). From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies. Macromolecules, 45(5), 2509–2513. https://doi.org/10.1021/ma3002092
Godeau, Guilhem, Laurence Navailles, Frédéric Nallet, Xinrong Lin, Thomas J. McIntosh, and Mark W. Grinstaff. “From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies.” Macromolecules 45, no. 5 (March 13, 2012): 2509–13. https://doi.org/10.1021/ma3002092.
Godeau G, Navailles L, Nallet F, Lin X, McIntosh TJ, Grinstaff MW. From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies. Macromolecules. 2012 Mar 13;45(5):2509–13.
Godeau, Guilhem, et al. “From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies.” Macromolecules, vol. 45, no. 5, Mar. 2012, pp. 2509–13. Pubmed, doi:10.1021/ma3002092.
Godeau G, Navailles L, Nallet F, Lin X, McIntosh TJ, Grinstaff MW. From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies. Macromolecules. 2012 Mar 13;45(5):2509–2513.
Published In
Macromolecules
DOI
ISSN
0024-9297
Publication Date
March 13, 2012
Volume
45
Issue
5
Start / End Page
2509 / 2513
Location
United States
Related Subject Headings
- Polymers
- 40 Engineering
- 34 Chemical sciences
- 09 Engineering
- 03 Chemical Sciences