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Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases

Publication ,  Journal Article
Spicer, LD
Published in: Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
December 1, 1978

The average energy of reaction for recoil hot species in a well scavenged system is defined explicitly and calculated for recoil tritium for hydrogen replacement reactions with cyclohexane and n-butane as a function of noble gas moderation. In general this average reaction energy is relatively independent of the composition of the system. However, in cases of high reactivity or low threshold energies for hot reaction where the primary reactive process competes significantly with thermal scavenging, more significant composition dependencies may be manifest. The generality of the method outlined is specifically dependent on the availability of information on the energy dependence of the cross sections for the reactions of interest.

Duke Scholars

Published In

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

DOI

ISSN

0300-9238

Publication Date

December 1, 1978

Volume

74

Start / End Page

527 / 532
 

Citation

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Spicer, L. D. (1978). Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases. Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 74, 527–532. https://doi.org/10.1039/F29787400527
Spicer, L. D. “Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases.” Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics 74 (December 1, 1978): 527–32. https://doi.org/10.1039/F29787400527.
Spicer LD. Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases. Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics. 1978 Dec 1;74:527–32.
Spicer, L. D. “Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases.” Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, vol. 74, Dec. 1978, pp. 527–32. Scopus, doi:10.1039/F29787400527.
Spicer LD. Calculation of the average energy of recoil hot reactions. Hot hydrogen replacement reactions in alkane systems moderated with noble gases. Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics. 1978 Dec 1;74:527–532.

Published In

Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics

DOI

ISSN

0300-9238

Publication Date

December 1, 1978

Volume

74

Start / End Page

527 / 532