Plasmonics quenching and enhancement of a fluorescing molecule outside and inside a silver metallic nanoshell
Analytic expressions are derived for the enhancement and quenching of a fluorescing molecule outside and in the interior of a metallic spherical nanoshell. The competing effects of enhancement and quenching are a strong function of the radial location of a molecule exterior to the shell. For a fluorescing molecule inside the shell, the enhancement and quenching are a weaker function of radius and a stronger function of the shell thickness. The enhancement and quenching also have a strong wavelength dependence arising from plasmon resonances excited within the particle. For an external molecule, a shell produces a larger peak enhancement than a solid homogeneous sphere of the same diameter. Calculations are presented to illustrate these effects in a silver shell. © 2011 IEEE.
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- Nanoscience & Nanotechnology
- 4009 Electronics, sensors and digital hardware
- 1007 Nanotechnology
- 0906 Electrical and Electronic Engineering
- 0303 Macromolecular and Materials Chemistry
Citation
Published In
DOI
ISSN
Publication Date
Volume
Issue
Start / End Page
Related Subject Headings
- Nanoscience & Nanotechnology
- 4009 Electronics, sensors and digital hardware
- 1007 Nanotechnology
- 0906 Electrical and Electronic Engineering
- 0303 Macromolecular and Materials Chemistry