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“[Cp*CoCoCp*]” is a Hydride

Publication ,  Journal Article
Kersten, JL; Rheingold, AL; Theopold, KH; Casey, CP; Widenhoefer, RA; Hop, CECA
Published in: Angewandte Chemie International Edition in English
January 1, 1992

The supposed synthesis of the cobalt complex [Cp*CoCoCp*] was in the spotlight at the end of last year (Angew. Chem. Int. Ed. Engl. 1991, 30, 1124). But the compound described at that time is actually the mixed‐valent cobalt hydride 2. The reaction of the dinuclear complex 1 with LiAlH4 yields two paramagnetic cobalt complexes (2 and 3), which have been fully characterized by X‐ray crystallography and spectroscopic methods, as well as by protonation and carbonylation. See also the Corrigendum on p. 1392. (Formula Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany

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Published In

Angewandte Chemie International Edition in English

DOI

EISSN

1521-3773

ISSN

0570-0833

Publication Date

January 1, 1992

Volume

31

Issue

10

Start / End Page

1341 / 1343
 

Citation

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Kersten, J. L., Rheingold, A. L., Theopold, K. H., Casey, C. P., Widenhoefer, R. A., & Hop, C. E. C. A. (1992). “[Cp*CoCoCp*]” is a Hydride. Angewandte Chemie International Edition in English, 31(10), 1341–1343. https://doi.org/10.1002/anie.199213411
Kersten, J. L., A. L. Rheingold, K. H. Theopold, C. P. Casey, R. A. Widenhoefer, and C. E. C. A. Hop. ““[Cp*CoCoCp*]” is a Hydride.” Angewandte Chemie International Edition in English 31, no. 10 (January 1, 1992): 1341–43. https://doi.org/10.1002/anie.199213411.
Kersten JL, Rheingold AL, Theopold KH, Casey CP, Widenhoefer RA, Hop CECA. “[Cp*CoCoCp*]” is a Hydride. Angewandte Chemie International Edition in English. 1992 Jan 1;31(10):1341–3.
Kersten, J. L., et al. ““[Cp*CoCoCp*]” is a Hydride.” Angewandte Chemie International Edition in English, vol. 31, no. 10, Jan. 1992, pp. 1341–43. Scopus, doi:10.1002/anie.199213411.
Kersten JL, Rheingold AL, Theopold KH, Casey CP, Widenhoefer RA, Hop CECA. “[Cp*CoCoCp*]” is a Hydride. Angewandte Chemie International Edition in English. 1992 Jan 1;31(10):1341–1343.
Journal cover image

Published In

Angewandte Chemie International Edition in English

DOI

EISSN

1521-3773

ISSN

0570-0833

Publication Date

January 1, 1992

Volume

31

Issue

10

Start / End Page

1341 / 1343