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Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate

Publication ,  Journal Article
Urano, Y; Higuchi, T; Hirobe, M; Nagano, T
Published in: Chemtracts
May 1, 1998

These researchers provide experimental evidence which shows that the influence of thiolate ligation on the oxidizing ability of the high-valent oxo-iron intermediate likely comes from the ability of the thiolate ligand to stabilize an oxygen radical structure (Scheme 1; L = S-; species B).

Duke Scholars

Published In

Chemtracts

ISSN

1431-9268

Publication Date

May 1, 1998

Volume

11

Issue

5

Start / End Page

327 / 332

Related Subject Headings

  • Organic Chemistry
 

Citation

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ICMJE
MLA
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Urano, Y., Higuchi, T., Hirobe, M., & Nagano, T. (1998). Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate. Chemtracts, 11(5), 327–332.
Urano, Y., T. Higuchi, M. Hirobe, and T. Nagano. “Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate.” Chemtracts 11, no. 5 (May 1, 1998): 327–32.
Urano Y, Higuchi T, Hirobe M, Nagano T. Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate. Chemtracts. 1998 May 1;11(5):327–32.
Urano, Y., et al. “Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate.” Chemtracts, vol. 11, no. 5, May 1998, pp. 327–32.
Urano Y, Higuchi T, Hirobe M, Nagano T. Pronounced axial thiolate ligand effect on the reactivity of high-valent oxo-iron porphyrin intermediate. Chemtracts. 1998 May 1;11(5):327–332.

Published In

Chemtracts

ISSN

1431-9268

Publication Date

May 1, 1998

Volume

11

Issue

5

Start / End Page

327 / 332

Related Subject Headings

  • Organic Chemistry