Journal articleJournal of Membrane Science · July 1, 2026
Polymeric ultrafiltration and microfiltration membranes are crucial for water treatment but produce growing amounts of plastic waste at end-of-life (EoL). While recent studies emphasize green solvents and bio-based polymers, the influence of disposal pathw ...
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Journal articleRsc Sustainability · July 1, 2026
The fabrication of semiconductor devices, particularly those used in flat-panel displays, is one of the significant climate-change challenges identified by the US Environmental Protection Agency (EPA) due to the associated greenhouse gas emissions. This st ...
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Journal articleEnvironmental science & technology · June 2026
Carbon-based nanomaterials (CBNMs) are promising agricultural amendments, yet predicting their transport and retention in heterogeneous soils remains challenging. In this study, we evaluated the colloidal stability and heteroaggregation of a commercial oxi ...
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Journal articleWater research · June 2026
The environmental degradation of polyethylene (PE) plastic is commonly described as a slow fragmentation process, generated by radical oxidation induced by sunlight, followed by gradual release of additives. Here, we challenge this view by applying a micro ...
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Journal articleEnvironmental science & technology · May 2026
Understanding how plastics degrade and fragment, releasing microplastics, nanoplastics, and dissolved organic carbon (DOC), is crucial for their risk assessment. This study assesses abiotic hydrolytic aging of polymer powders (40-700 μm) under OECD guideli ...
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Journal articleEnvironmental science & technology · May 2026
The environmental fate of phosphorus in shallow aquatic systems is closely linked to the properties of iron (oxyhydr)oxide minerals such as goethite, which can bind phosphate and influence its mobility. This study investigates how light exposure during min ...
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Journal articleApplied and environmental microbiology · March 2026
The built environment (BE), where we spend the majority of our time, contains a variety of surfaces with distinct properties. Our understanding of how these surfaces shape the microbiome of the BE (MoBE) is underdeveloped and limits the ability to develop ...
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Journal articleChemical Engineering Journal · February 15, 2026
Microplastic and nanoplastic (MNP) pollution has become a global environmental concern, with laundry wastewater identified as a major point source of fibrous MNPs that are insufficiently removed using conventional wastewater treatment processes. This revie ...
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Journal articleMicroplastics and Nanoplastics · December 1, 2025
Depending on the environmental compartment, plastics are subjected to various stressors, including UV light, water, microbial exudates (enzymes), and temperature. Among these, stress on plastics from photo-chemical processes was identified as a leading exp ...
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Journal articleJournal of hazardous materials · December 2025
Microplastics (MPs) are often regarded as pollutants vectors, yet they undergo substantial physicochemical transformations in aquatic environments. Here, we reveal how photo-oxidation (UVs) and mechanical stress transform polyethylene-based-MPs into reacti ...
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Journal articleEnvironmental toxicology and chemistry · December 2025
A realistic release estimation is key when assessing whether the use of a chemical can be considered environmentally safe. For practically all industrial, professional, and consumer use patterns, air emission measurements are absent or available for only o ...
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Journal articleOne Earth · November 21, 2025
The diverse material properties of plastic polymers have prompted their extensive use, resulting in widespread pollution, including environmental contamination by chemical additives used to enhance polymer properties. Additives have diverse biological impa ...
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Journal articleJournal of hazardous materials · November 2025
Plastics degrade in the environment through complex physical and chemical processes. Here, we demonstrate that nanoplastics (NPs) can be directly released from macroplastics, and not solely generated via intermediate microplastic (MP) fragmentation, thereb ...
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Journal articleJournal of hazardous materials · September 2025
Microplastic particles (MPs) are efficiently transferred from wastewater to sludge during wastewater treatment, but it remains unclear to what extent the physical-chemical properties (e.g., polymer type, shape, size) of the MPs affect their incorporation i ...
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Journal articleEnvironmental Science and Technology Letters · July 8, 2025
Emergence of a new class of nanoscaled contaminants, such as micro- and nanoplastics, as well as nanotechnology’s current transition into advanced materials have broadened the boundaries of the field. These field-expanding topics exemplify the core role of ...
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Journal articleEnvironmental science & technology · March 2025
Here, we assessed the heteroaggregation of polystyrene (PS) and poly(vinyl chloride) (PVC) nanoplastics with SiO2 as a model of natural colloids. Homoaggregation and heteroaggregation were evaluated as a function of CaCl2 (0-100 mM) a ...
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Journal articleEnvironmental technology · February 2025
In this study, we experimentally investigate the production and characterization of CaCO3 particles through the carbonation process of Ca(OH)2 and evaluate their potential application in removing organic matter. The CaCO3 p ...
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Journal articleBeilstein journal of nanotechnology · January 2025
Nanosafety assessment, which seeks to evaluate the risks from exposure to nanoscale materials, spans materials synthesis and characterisation, exposure science, toxicology, and computational approaches, resulting in complex experimental workflows and diver ...
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Journal articleNanoImpact · October 2024
Lessons learned, methodologies, and application of tools that have been developed within the context of research on the environmental impacts, health, and safety of nanomaterials (nano-EHS) provide a solid foundation for research on nano/microplastics. In ...
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Journal articleSeparation and Purification Technology · August 9, 2024
Nanomaterials, added in small quantities as “nanofillers,” have been shown to improve the performance of NF membranes in terms of mechanical properties, anti-fouling characteristics, selectivity, and transport. The goal of this work is to explore the mecha ...
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Journal articleEnvironmental Science Nano · July 3, 2024
Polymer nanocomposites have diverse industrial and commercial uses. While many toxicity studies have assessed the individual materials (e.g., polymer, nanomaterial) comprising nanocomposites, few have examined the potential toxicity of the nanocomposite as ...
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Journal articleEnvironmental Science Nano · June 7, 2024
Nanomaterials are used in polymer composites to enhance plastic products' properties. Silver nanoparticles (AgNPs) are added to composites for their antimicrobial and fungicidal properties. Polyethylene terephthalate glycol polymer (PETG) AgNP composite te ...
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Journal articleScientific data · February 2024
Predicting and elucidating the impacts of materials on human health and the environment is an unending task that has taken on special significance in the context of nanomaterials research over the last two decades. The properties of materials in environmen ...
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Journal articleMethods in molecular biology (Clifton, N.J.) · January 2024
Bacterial membrane vesicles (BMVs) are extracellular vesicles secreted by either Gram-positive or Gram-negative bacteria. These BMVs typically possess a diameter between 20 and 250 nm. Due to their size, when these BMVs are suspended in another medium, the ...
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Journal articleEnviron Sci Technol · November 7, 2023
There is a long-standing appreciation among environmental engineers and scientists regarding the importance of biologically derived colloidal particles and their environmental fate. This interest has been recently renewed in considering bacteriophages and ...
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Journal articleEnviron Sci Technol · September 5, 2023
Extracellular vesicles (EVs) are membrane-bounded, nanosized particles, produced and secreted by all biological cell types. EVs are ubiquitous in the environment, operating in various roles including intercellular communication and plant immune modulation. ...
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Journal articleColloids Surf B Biointerfaces · May 2023
Extracellular vesicles (EVs) are nano-sized, biocolloidal proteoliposomes that have been shown to be produced by all cell types studied to date and are ubiquitous in the environment. Extensive literature on colloidal particles has demonstrated the implicat ...
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Journal articleMicroplastics and nanoplastics · January 2023
A majority of American adults report having used sex toys, which, by design, interact with intimate and permeable body parts yet have not been subject to sufficient risk assessment or management. Physical and chemical data are presented examining potential ...
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Journal articleFrontiers in Physics · January 1, 2023
Introduction: Significant progress has been made in terms of best practice in research data management for nanosafety. Some of the underlying approaches to date are, however, overly focussed on the needs of specific research projects or aligned to a single ...
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Journal articleEnvironmental science & technology · November 2022
Extracellular antibiotic resistance genes (eARGs) are widespread in the environment and can genetically transform bacteria. This work examined the role of environmentally relevant nanoparticles (NPs) in regulating eARG bioavailability. eARGs extracted from ...
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Journal articleThe Science of the total environment · August 2022
Chemical ingredients in consumer products are continually changing. To understand our exposure to chemicals and their consequent risk, we need to know their concentrations in products, or chemical weight fractions. Unfortunately, manufacturers rarely repor ...
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Journal articleEnvironmental science & technology · July 2022
This work tests the reliability of a simple, rapid centrifugal technique to estimate the removal force necessary to detach common airborne particles from the surface of a photovoltaic panel. Previously, we have used atomic force microscopy (AFM) to obtain ...
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Journal articleDesalination · June 15, 2022
An understanding of how nanomaterials, serving as “nanofillers” in nanocomposite membranes, affect membrane performance is limited. This study investigates the mechanisms by which nanomaterials affect membrane performance from a paired modeling and experim ...
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Journal articleWater research · June 2022
The validity and usefulness of implementing bacteriophages into water treatment systems as agents of targeted bacterial inactivation is yet to be determined. While some concerns are still more purely biological in nature other concerns are still chiefly ro ...
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Journal articleProcess Safety and Environmental Protection · May 1, 2022
Pre-concentration and separation processes of Rare Earth Elements (REEs) were investigated in terms of several factors. Nitric acid leachate of e-waste was first pre-treated by increasing pH and filtering through microfiltration. For pre-concentration, pre ...
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Journal articleChemosphere · April 2022
Limited natural resources and a continuous increase in the demand for modern technological products, is creating a demand and supply gap for rare earth elements (REEs) and Sc. There is therefore a need to adopt the sustainable approach of the circular econ ...
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Journal articleEnvironmental technology · March 2022
Micelle enhanced ultrafiltration (MEUF) is a surfactant-based membrane separation process that may be used to separate target ions from mixed metal aqueous solutions, such as leachates of coal ash and other geological wastewaters. The ability of MEUF to se ...
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Journal articleThe Science of the total environment · March 2022
Microplastics (MPs) have become an emerging new pollutant of rising concern due to the exponential growth of plastics in consumer products. Most MP and nanoplastic pollution comes from the fragmentation of plastics through mechanical stress, chemical react ...
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Journal articleEnvironmental science and pollution research international · January 2022
E-waste (EW) from discarded electrical and electronic devices is a potential source of rare earth elements (REEs) that might be recovered from urban and industrial wastes. REEs are essential raw materials for emerging and high technologies. China currently ...
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Journal articleEnvironmental science & technology · January 2022
Silver nanoparticles (AgNPs) are extensively used in consumer products and biomedical applications, thus guaranteeing both environmental and human exposures. Despite extensive research addressing AgNP safety, there are still major knowledge gaps regarding ...
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Journal articleEnvironmental Engineering Science · December 1, 2021
Fate of extracellular antibiotic resistance genes (eARGs) - which are widespread in various environments - is dependent on gene persistence. This work examined the previously unconsidered role of environmentally relevant nanoparticles (NPs) in regulating e ...
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Journal articleNanotoxicology · December 2021
Polymer nanocomposites combine the versatile, lightweight characteristics of polymers with the properties of nanomaterials. Polyethylene terephthalate glycol (PETG) is commonly used in polymer additive manufacturing due to its controllable transparency, hi ...
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Journal articleEnvironmental science and pollution research international · November 2021
Rare earth elements or REEs are a vital and irreplaceable part of our modern technological and digital industries. Among the REEs that are the most critical to be recovered are Ce, La, and particularly, Nd, and Y, due to high demand and at a potential futu ...
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Journal articleEnvironmental science & technology · August 2021
Silver nanoparticles (AgNPs) are well-proven antimicrobial nanomaterials, yet little is elucidated regarding the mechanism underlying cytotoxicity induced by these nanoparticles. Here, we tested the hypothesis that mitochondria are primary intracellular ta ...
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Journal articleEnvironmental science & technology · August 2021
Manufactured nanomaterials (MNMs) are incorporated as "nanofillers" into consumer products to enhance properties of interest. Multiwalled carbon nanotubes (MWCNTs) are known for their unique properties and have many applications in polymers. However, the r ...
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Journal articleScience of the Total Environment · July 10, 2021
REEs are essential materials for modern technology due to their unmatched physical and chemical properties. This paper reviews the potential and types of rare earth elements (REE) in 32 different secondary sources that contain water, wastewater, and slime/ ...
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Journal articleNanoImpact · July 2021
The empirical necessity for integrating informatics throughout the experimental process has become a focal point of the nano-community as we work in parallel to converge efforts for making nano-data reproducible and accessible. The NanoInformatics Knowledg ...
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Journal articleEnvironmental science. Processes & impacts · May 2021
All cells produce extracellular vesicles (EVs). These biological packages contain complex mixtures of molecular cargo and have a variety of functions, including interkingdom communication. Recent discoveries highlight the roles microbial EVs may play in th ...
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Journal articleNature nanotechnology · May 2021
Increasing concern and research on the subject of plastic pollution has engaged the community of scientists working on the environmental health and safety of nanomaterials. While many of the methods developed in nano environment, health and safety work hav ...
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Journal articleThe Science of the total environment · March 2021
A relevant but yet unconsidered subset of particles that may alter the fate of extracellular antibiotic resistance genes (eARGs) are nano-scale particles (NPs), which are ubiquitous in natural environments and have unique properties. In this study, sorptio ...
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Journal articleEnvironmental science & technology · February 2021
The presence of biopolymers in surface waters and their significance for potable water supply have received little attention previously owing to their low concentrations. In this paper, we present the results of an extensive study that has investigated the ...
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Journal articleEnvironmental science & technology · February 2021
Eight types of common airborne particles were used to investigate whether the composition of dust influences its soiling potential on photovoltaic panels. Chosen model particles were roughly spherical, 10-30 μm in diameter to minimize the differences in si ...
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Journal articleJournal of Membrane Science · January 15, 2021
Protein fouling within a polymeric microfiltration membrane was characterized in situ and in real time with non-Faradaic electrochemical impedance spectroscopy (EIS). The polymeric membrane was prepared with a conductive gold coating, allowing the membrane ...
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Journal articleJournal of Membrane Science · January 1, 2021
Nanomaterials have been used in the formulation of thin-film composite (TFC) membranes to improve membrane performance and reduce environmental impact. Here we investigate the role of nanomaterial placement in the active layer versus the support layer of t ...
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Journal articleNanoImpact · January 2021
Engineered nanomaterials (ENMs) are intentionally designed and produced by humans to revolutionize the manufacturing sector, such as electronic goods, paints, tires, clothes, cosmetic products, and biomedicine. With the spread of these ENMs in our daily li ...
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Journal articleReviews of Geophysics · December 1, 2020
The consequences that engineered nanomaterials (ENMs) may cause in the environment have been under investigation for more than 15 years. Hundreds of millions of euros/dollars have been invested into safety issues of ENMs, and much progress has been made in ...
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Journal articleJournal of Applied Polymer Science · November 20, 2020
Nanoparticle (NP) additions can substantially improve the performance of reverse osmosis and nanofiltration polyamide (PA) membranes. However, the relative impacts of leading additives are poorly understood. In this study, we compare the effects of TiO
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Journal articleEnvironmental science & technology · November 2020
Chemical oxidation using peracetic acid (PAA) can be enhanced by activation with the formation of reactive species such as organic radicals (R-O•) and HO•. Thermal activation is an alternative way for PAA activation, which was first a ...
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Journal articleEnvironmental Science Nano · October 1, 2020
Silver nanomaterials with different shapes (spheres, plates, wires, rods, cubes) are valued by industries and scientists for their shape-dependent properties which make them useful for diverse applications. In a safer-by-design perspective, controlling the ...
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Journal articleSmall (Weinheim an der Bergstrasse, Germany) · September 2020
Nanotechnologies have reached maturity and market penetration that require nano-specific changes in legislation and harmonization among legislation domains, such as the amendments to REACH for nanomaterials (NMs) which came into force in 2020. Thus, an ass ...
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Journal articlePolymer Bulletin · July 1, 2020
Nano-TiO2 nanoparticles were incorporated into thin film nanocomposites (TFN) formed on hollow fiber support membranes composed of a blend of polysulfone and multi-walled carbon nanotubes. Three different TiO2 nanoparticles (0.01%, 0. ...
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Journal articleEnvironmental Science Nano · June 1, 2020
Few standardized methods and reference systems have been established for evaluating the behavior of engineered nanomaterials in complex media like natural soils. In this study, a working method for a functional assay to determine the affinity of nanopartic ...
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Journal articleJournal of Membrane Science · March 15, 2020
This paper presents an investigation of the variation in membrane characteristics and formation of halogenated by-products during the off-line chemical cleaning of algae-fouled ultrafiltration (UF) membrane by NaClO solution. The chemical treatment led to ...
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Journal articleWater research · March 2020
Targeted inactivation of bacteria using bacteriophages has been proposed in applications ranging from bioengineering and biofuel production to medical treatments. The ability to differentiate between desirable and undesirable organisms, such as in targetin ...
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Journal articleACS nano · March 2020
Crop disease control is crucial for the sustainable development of agriculture, with recent advances in nanotechnology offering a promising solution to this pressing problem. However, the efficacy of nanoparticle (NP) delivery methods has not been fully ex ...
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Journal articleEnvironmental science & technology · February 2020
Reliable predictions of the environmental fate and risk of engineered nanomaterials (ENMs) require a better understanding of ENM reactivity in complex, biologically active systems for chronic low-concentration exposure scenarios. Here, simulated freshwater ...
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Journal articleChemico-biological interactions · January 2020
The extensive use of silver nanoparticles (AgNPs) in manufactured products will inevitably increase environmental exposure, highlighting the importance of accurate toxicity assessments. A frequent strategy to estimate AgNP cytotoxicity is to use absorbance ...
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Journal articleEnvironmental science & technology · January 2020
An advanced oxidation process of combining cobalt and peracetic acid (Co/PAA) was developed to degrade sulfamethoxazole (SMX) in this study. The formed acetylperoxy radical (CH3CO3•) through the activation of PAA by Co (Co< ...
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Journal articleEnvironmental science & technology · January 2020
The application of nanoscale zerovalent iron (nano-ZVI) particles for groundwater remediation has spurred research into the influence of the collector heterogeneity on the nano-ZVI mobility. The chemical heterogeneity of surfaces within aquifer media affec ...
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Journal articleEnvironmental Science Nano · January 1, 2020
The chemical composition and properties of environmental media determine nanomaterial (NM) transport, fate, biouptake, and organism response. To compare and interpret experimental data, it is essential that sufficient context be provided for describing the ...
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Journal articleComputational and structural biotechnology journal · January 2020
Nanotechnology has enabled the discovery of a multitude of novel materials exhibiting unique physicochemical (PChem) properties compared to their bulk analogues. These properties have led to a rapidly increasing range of commercial applications; this, howe ...
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Journal articleChemosphere · December 2019
The effect of zinc oxide nanoparticles (ZnO NPs) and zinc sulfide nanoparticles (ZnS NPs) on the toxicity of sewage sludges in sewage sludge-amended soils was investigated with respect to plant- (Lepidium sativum) and soil- (Folsomia candida) species. The ...
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Journal articleChemosphere · July 2019
Phosphorus release is one of the disadvantages during worm predation, which has an adverse effect on wastewater treatment. In order to investigate and reveal the effects and mechanisms of worm predation on phosphorus transformation, batch experiments were ...
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Journal articleWater research · July 2019
In this study, ultraviolet based advanced oxidation processes (UV-AOPs) including UV/persulfate (UV/PS), UV/chlorine, and UV/H2O2 were employed to alleviate ultrafiltration membrane fouling during the treatment of algae-laden water. T ...
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Journal articleJournal of hazardous materials · June 2019
High concentrations of pesticides enter surface waters following agricultural application, raising environmental and human health concerns. The use of photoreactive nanoparticles has shown promise for contaminant degradation and surface water remediation. ...
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Journal articleEnvironment international · June 2019
Membrane fouling is one of the biggest challenges in the widespread application of membrane bioreactors. In this study, a combined system of anaerobic-anoxic-oxic membrane bioreactor (A2O-MBR) and worm reactor (WR) was established for fouling co ...
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Journal articleEnvironmental science & technology · April 2019
Coal combustion residues and other geological waste materials have been proposed as a resource for rare earth elements (REEs, herein defined as the 14 stable lanthanides, yttrium, and scandium). The extraction of REEs from residues often generate acidified ...
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Journal articleEnvironmental science & technology · March 2019
Here, we present a model for the prediction of nanoparticle fate in aquatic environments, parametrized using functional assays that take into account conditions of the environmental media and nanoparticle properties. The model was used to explore scenarios ...
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Journal articlePolymer Testing · February 1, 2019
The control of thin film nanocomposite (TFN) membranes cross-linking degree is an important factor to design new membranes and optimizing permeation characteristics. The Fe3O4 nanoparticle's based TFN membranes due to potentially adde ...
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Journal articleNanoimpact · January 1, 2019
Environmental risk assessment of nanomaterials generally relies on a decision-tree based strategy which provides guidance and protocols for the determination of a collection of hazard end-points. Mesocosm testing is based on a different approach. This meth ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · December 2018
The use of plasmonic nanoplatforms has received increasing interest in a wide variety of fields ranging from theranostics to environmental sensing to plant biology. In particular, the development of plasmonic nanoparticles into ordered nanoclusters has bee ...
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Journal articleNature nanotechnology · November 2018
Predicting nanoparticle fate in aquatic environments requires mimicking of ecosystem complexity to observe the geochemical processes affecting their behaviour. Here, 12 nm Au nanoparticles were added weekly to large-scale freshwater wetland mesocosms. Afte ...
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Journal articleChemical Engineering Journal · October 1, 2018
This work evaluated nanofiltration (NF) as a potential step in the recovery process of Rare Earth Elements (REEs) from leachates of coal combustion fly ashes. A pre-treatment step, by pH adjustment and microfiltration (MF), has been studied to separate REE ...
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Journal articleEnvironmental science & technology · October 2018
To achieve greater separation performance and antifouling properties in a thin-film composite (TFC) nanofiltration membrane, cellulose nanocrystals (CNCs) were incorporated into the polyamide layer of a TFC membrane for the first time. The results of Fouri ...
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Journal articleEcological applications : a publication of the Ecological Society of America · September 2018
Despite the rapid rise in diversity and quantities of engineered nanomaterials produced, the impacts of these emerging contaminants on the structure and function of ecosystems have received little attention from ecologists. Moreover, little is known about ...
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Journal articleEnvironmental science & technology · September 2018
Trace metals associated with nanoparticles are known to possess reactivities that are different from their larger-size counterparts. However, the relative importance of small relative to large particles for the overall distribution and biouptake of these m ...
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Journal articleJournal of Composite Materials · May 1, 2018
The magnetic response of a polyamide nanocomposite membrane under applying a magnetic field has been modeled to evaluate elastic deformation order of magnitude. A PA-Fe3O4 nanocomposite membrane is considered to be modeled under influ ...
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Journal articleEnvironmental science & technology · April 2018
During nanoparticle environmental exposure, presence in the water column is expected to dominate long distance transport as well as initial aquatic organism exposure. Much work has been done to understand potential ecological and toxicological effects of t ...
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Journal articleEnvironmental science & technology · March 2018
Silver nanoparticles (AgNPs) are increasingly used in consumer products, biotechnology, and medicine, and are released into aquatic ecosystems through wastewater discharge. This study investigated the phytotoxicity of AgNPs to aquatic plants, Egeria densa ...
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Journal articleChemical Engineering Journal · January 15, 2018
A nucleophilic aromatic substitution reaction was proposed to synthesize porous carbon nanotubes (CNTs) to avoid their aggregation in solution. Hydroxylated carbon nanotubes (CNTs-OH) were reacted with different concentrations of rigid decafluorobiphenyl ( ...
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Journal articleAquat Toxicol · January 2018
Plastic pollution is a critical environmental concern and comprises the majority of anthropogenic debris in the ocean, including macro, micro, and likely nanoscale (less than 100nm in at least one dimension) plastic particles. While the toxicity of macropl ...
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Journal articleEnvironmental Science Nano · January 1, 2018
A simple method for the preparation of a three-dimensional (3D) reduced graphene oxide/Fe3O4 (3D-rGO/Fe3O4) hybrid hydrogel was developed via the reduction of graphene oxide by ferrous ions and in situ simultaneo ...
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Journal articleEnvironmental science & technology · November 2017
As process-based environmental fate and transport models for engineered nanoparticles are developed, there is a need for relevant and reliable measures of nanoparticle behavior. The affinity of nanoparticles for various surfaces (α) is one such measure. Me ...
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Journal articleEnvironmental science & technology · November 2017
Direct contact membrane distillation (DCMD) is an emerging water treatment technology that has high salt rejection; however, its commercialization potential for applications such as seawater desalination or industrial wastewater reuse may be limited by low ...
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Journal articleEnvironmental science & technology · August 2017
Nanoscale particles have the potential to modulate the transport, lifetimes, and ultimate uptake of pesticides that may otherwise be bound to agricultural soils. Engineered nanoparticles provide a unique platform for studying these interactions. In this st ...
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Journal articleEnvironmental science & technology · August 2017
The affinity between nanoscale zerovalent iron (nano-ZVI) and mineral surfaces hinders its mobility, and hence its delivery into contaminated aquifers. We have tested the hypothesis that the attachment of poly(acrylic acid)-coated nano-ZVI (PAA-nano-ZVI) t ...
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Journal articleEnvironmental science. Nano · June 2017
Zero-valent iron nanoparticles (nano-ZVIs) have been widely studied for in situ remediation of groundwater and other environmental matrices. Nano-ZVI particle mobility and reactivity are still the main impediments in achieving efficient in situ
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Journal articleEnvironmental science & technology · May 2017
Aquatic ecosystems are expected to receive Ag0 and Ag2S nanoparticles (NPs) through anthropogenic waste streams. The speciation of silver in Ag-NPs affects their fate in ecosystems, but its influence on interactions with aquatic plant ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · March 2017
The influence of inorganic anions on the photoreactivity and aggregation of titanium dioxide nanoparticles (NPs) was assessed by dosing carbonate, chloride, nitrate, phosphate, and sulfate as potassium salts at multiple concentrations. NP stability was mon ...
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Journal articleEnvironmental science & technology · January 2017
Transport of negatively charged nanoparticles in porous media is largely affected by cations. To date, little is known about how cations of the same valence may affect nanoparticle transport differently. We observed that the effects of cations on the trans ...
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Journal articleEnvironmental Science Nano · January 1, 2017
The agro-ecosystem is under enormous pressure due to rapid population growth, increasing global food demand, increasing fresh water withdrawals and energy consumption, excessive food waste, inefficient use of agrochemicals, environmental degradation and cl ...
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Journal articleEnvironmental science & technology · January 2017
The inherent properties of hydrophilicity and mechanical strength of cellulose nanocrystals (CNCs) make them a possible alternative to carbon nanotubes (CNTs) that may present fewer objections to application water-treatment membranes. In this work, the hyd ...
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Journal articleJournal of biomedical nanotechnology · December 2016
Cerium dioxide nanoparticles (nanoceria), currently used as catalysts including additives to diesel fuel, also present potential as a novel therapeutic agent for disorders involving oxidative stress. However, little is known about the effects of nanoceria ...
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Journal articleNanotoxicology · November 2016
Silver nanoparticles (AgNPs) have been increasingly commercialized and their release into the environment is imminent. Toxicity of AgNP has been studied with a wide spectrum of organisms, yet the mechanism of toxicity remains largely unknown. This study sy ...
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Journal articleWater research · November 2016
Chemical cleaning of membranes may be limited by the tolerance of some polymeric membranes to chlorine. In this work we show that modification of a polyvinyl pyrrolidone-polysulfone (PVP-PSF) membrane with carboxylated carbon nanotubes (CNTs) leads to grea ...
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Journal articleScientific reports · October 2016
This paper aimed to investigate the influences of operational parameters and aqueous chemical conditions on transport behaviors of cerium oxides nanoparticles (CeO2-NPs) in saturated silica media. Results indicated that increasing rates of attac ...
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Journal articleThe Science of the total environment · September 2016
The increasing use of strategies incorporating nanoscale zero valent iron (nZVI) for soil and groundwater in situ remediation is raising some concerns regarding the potential adverse effects nZVI could have on indigenous microbial communities and ecosystem ...
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Journal articleEcotoxicology (London, England) · August 2016
The influence of salinity on Ag toxicity was investigated in Atlantic killifish (Fundulus heteroclitus) early life-stages. Embryo mortality was significantly reduced as salinity increased and Ag(+) was converted to AgCl(solid). However, as salinity continu ...
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Journal articleEnvironmental science & technology · July 2016
Nanoscale materials, whether natural, engineered, or incidental, are increasingly acknowledged as important components in large, environmental systems with potential implications for environmental impact and human health. Mathematical models are a useful t ...
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Journal articleChemical Engineering Journal · June 15, 2016
A simple and convenient method was used to prepare novel granular carbon nanotubes (CNTs) for enhanced adsorption of pharmaceuticals. By heating CNTs powder at 450 °C in air, followed by filtration, the obtained granular adsorbent exhibited high surface ar ...
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Journal articleEnvironmental science & technology · June 2016
Engineered nanomaterials (ENMs) are increasingly entering the environment with uncertain consequences including potential ecological effects. Various research communities view differently whether ecotoxicological testing of ENMs should be conducted using e ...
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Journal articleJournal of hazardous materials · March 2016
Ball milling was used to prepare two ultrafine magnetic biochar/Fe3O4 and activated carbon (AC)/Fe3O4 hybrid materials targeted for use in pharmaceutical removal by adsorption and mechanochemical degradation of pharmaceutical compounds. Both hybrid adsorbe ...
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Journal articleNanotoxicology · January 2016
Uptake, transport and toxicity of engineered nanomaterials (ENMs) into plant cells are complex processes that are currently still not well understood. Parts of this problem are the multifaceted plant anatomy, and analytical challenges to visualize and quan ...
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Journal articleEnvironmental Science Nano · January 1, 2016
The complexity of engineered nanomaterials with regard to their structure and system-dependent properties, and limits of instrumentation to fully characterize nanomaterials in aqueous suspensions or biological media make it difficult to understand how mate ...
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Journal articleThe Science of the total environment · December 2015
The study of nanomaterial impacts on environment, health and safety (nanoEHS) has been largely predicated on the assumption that exposure and hazard can be predicted from physical-chemical properties of nanomaterials. This approach is rooted in the view th ...
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Journal articleJournal of Membrane Science · September 1, 2015
In this work, the release of organic compounds, the variations of membrane properties and the formation of toxic byproducts during chlorine treatment of polyvinyl pyrrolidone-polysulfone (PVP-PSF) membranes were investigated. Chlorine treatment decreased b ...
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Journal articleEnvironmental pollution (Barking, Essex : 1987) · August 2015
Wastewater Treatment Plants (WWTPs) are a key pathway by which nanoparticles (NPs) enter the environment following release from NP-enabled products. This work considers the fate and exposure of CeO2 NPs in WWTPs in a two-step process of heteroaggregation w ...
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Journal articleEnvironmental engineering science · August 2015
Addition of nanoscale zero valent iron (NZVI) to anaerobic batch reactors to enhance methanogenic activity is described. Two NZVI systems were tested: a commercially available NZVI (cNZVI) slurry and a freshly synthesized NZVI (sNZVI) suspension that was p ...
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Journal articleChemical Engineering Journal · July 1, 2015
The generation of reactive species in titanium dioxide (TiO2) nanoparticle photocatalysis was assessed in a laboratory scale setup, in which P25 Aeroxide TiO2 suspensions were photoactivated by means of UV-A radiation. Photogenerated ...
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Journal articleEnvironmental science & technology · July 2015
Terrestrial crops are directly exposed to silver nanoparticles (Ag-NPs) and their environmentally transformed analog silver sulfide nanoparticles (Ag2S-NPs) when wastewater treatment biosolids are applied as fertilizer to agricultural soils. This leads to ...
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Journal articleEnvironmental science & technology · May 2015
Cellulose nanomaterials are naturally occurring with unique structural, mechanical and optical properties. While the paper and packaging, automotive, personal care, construction, and textiles industries have recognized cellulose nanomaterials' potential, w ...
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Journal articleThe Science of the total environment · April 2015
The use of nano-enabled materials in industry and consumer products is increasing rapidly and with it, the more imperative it becomes to understand the consequences of such materials entering the environment during production, use or disposal. The novel pr ...
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Journal articleDesalination · March 2, 2015
Pilot scale studies were performed to investigate how CNTs might affect hollow fiber membrane (HF) resistance to stress. Further, this research explored how the addition of CNTs into membrane solutions affected trends associated with changes in conventiona ...
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Journal articleWater research · February 2015
2-methylisoborneol (2-MIB) and geosmin are two odor-causing compounds that are difficult to remove and the cause of many consumer complaints. In this study, we assessed the degradation of 2-MIB and geosmin using a UV/persulfate process for the first time. ...
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Journal articleACS applied materials & interfaces · February 2015
The development of a sustainable membrane surface based on chitosan/poly(acrylic acid) (CHI/PAA) multilayers suitable for applications in analytical separations is reported here. Bilayers are constructed on polyamide microfiltration membranes at a pH combi ...
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Journal articleJournal of hazardous materials · January 2015
A nano-composite device composed of nano-scale zerovalent iron (ZVI) and C60 fullerene aggregates (ZVI/nC60) was produced via a rapid nucleation method. The device was conceived to deliver reactive oxygen species (ROS) generated by photosensitization and/o ...
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Journal articleComptes Rendus Geoscience · January 1, 2015
Interdisciplinarity is of first importance to evaluate the risks associated with nanotechnology. The reasons are that nanomaterials are very new materials that combine nano-sizes and new reactivities. The complexity comes from the very low concentrations o ...
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Journal articleParticle and fibre toxicology · December 2014
BackgroundAirborne exposure to nanomaterials from unintended occupational or environmental exposures or as a consequence of product use may lead to adverse health effects. Numerous studies have focused on single-walled carbon nanotubes (SWCNTs) an ...
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Journal articleEnvironmental Science Nano · December 1, 2014
We report here the first studies addressing fate and transport of single walled carbon nanotubes (SWNTs) in aquatic mesocosms. The experimental design was structured to study the impact of nanomaterials within a tightly controlled and highly instrumented w ...
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Journal articleWater research · November 2014
Despite the growing use of carbon nanomaterials in commercial applications, very little is known about the fate of these nanomaterials once they are released into the environment. The carbon-carbon bonding of spherical sp(2) hybridized fullerene (C60) form ...
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Journal articleNanotoxicology · August 2014
We assessed the biodistribution and in situ speciation of sub-lethal concentrations of citrate-coated silver nanoparticles and dissolved silver within Fundulus heteroclitus embryos. Using a thorough physico-chemical characterization, we studied the role of ...
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Journal articleThe Science of the total environment · July 2014
The growing interest in nanoparticles (NP) is inevitably translating into an increase of their emissions in the environment. On the other hand, the necessary knowledge about the fate and transport of these NPs in the environment remains limited. In particu ...
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Journal articleEnvironmental science & technology · July 2014
Engineered nanomaterials (ENMs) are used to enhance the properties of many manufactured products and technologies. Increased use of ENMs will inevitably lead to their release into the environment. An important route of exposure is through the waste stream, ...
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Journal articleScientific reports · July 2014
Physical-chemists, (micro)biologists, and ecologists need to conduct meaningful experiments to study the environmental risk of engineered nanomaterials with access to relevant mechanistic data across several spatial and temporal scales. Indoor aquatic meso ...
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Journal articleEnvironmental Engineering Science · July 1, 2014
A confluence of water and silver-containing products or compounds results in unintentional or intentional discharge of silver species (including silver nanoparticles [AgNPs], free or organic matter-bound Ag+, Ag-halides, or soluble Ag-complexes) ...
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Journal articleEnvironmental Engineering Science · July 1, 2014
In this study, we present a method for determining the relative affinity of nanoparticles (NPs) for an ensemble of other particles in a complex, heterogeneous suspension. We evaluated this method for NPs heteroaggregating with suspended solids present in a ...
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Journal articleEnvironmental science & technology · May 2014
The use of antimicrobial silver nanoparticles (AgNPs) in consumer-products is rising. Much of these AgNPs are expected to enter the wastewater stream, with up to 10% of that eventually released as effluent into aquatic ecosystems with unknown ecological co ...
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Journal articleThe Science of the total environment · March 2014
The adaptive nature of the Forecasting the Impacts of Nanomaterials in the Environment (FINE) Bayesian network is explored. We create an updated FINE model (FINEAgNP-2) for predicting aquatic exposure concentrations of silver nanoparticles (AgNP) by combin ...
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Journal articleEnvironmental science & technology · March 2014
Significant progress has been made in understanding the toxicity of silver nanoparticles (Ag NPs) under carefully controlled laboratory conditions. Natural organic matter (NOM) is omnipresent in complex environmental systems, where it may alter the behavio ...
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Journal articleJournal of hazardous materials · January 2014
Interactions between organic matter (OM) and engineered polymer coatings as they affect the retention of polyvinylpyrrolidone (PVP) polymer-coated silver nanoparticles (AgNPs) were studied. Two distinct types of OM-cysteine representing low molecular weigh ...
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Journal articleAWWA Amta 2014 Membrane Technology Conference and Exposition · January 1, 2014
Ceramic membranes were treated with a hydrophobic coating for use in direct contact membrane distillation (DCMD). Two types of anodized aluminum oxide membranes and two pore sizes of a titanium dioxide-zirconium dioxide membrane were coated with a 1H,1H,2H ...
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Journal articleEnvironmental Chemistry · January 1, 2014
Environmental context The increasing use of engineered nanoparticles has led to concerns over potential exposure to these novel materials. Predictions of nanoparticle transport in the environment and exposure risks could be simplified if all nanoparticles ...
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Journal articleAmta AWWA Membrane Technology Conference and Exposition 2013 · December 19, 2013
Electrically conductive polymer-nanocomposite (ECPNC) reverse osmosis (RO) thin film membranes were demonstrated to have biofilm-preventing capabilities under extreme bacteria and organic material loadings. A simple route to the creation and application of ...
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Journal articleJournal of Membrane Science · November 5, 2013
Multiwalled carbon nanotubes (CNTs) carboxylated to varying weight percentages were added to polysulfone membranes. The degree to which the CNTs were retained within the membrane during membrane production, operation and cleaning was examined as a function ...
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Journal articleSurface Innovations · September 1, 2013
There is an urgent need for low-cost and low-toxicity antimicrobial agents for water treatment and medical applications. Current approaches utilize relatively expensive and corrosive chemicals and disinfectants to reduce, prevent or remove biofilms in tech ...
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Journal articleChemical Engineering Journal · August 15, 2013
The effects of two types of organic matter (OM) (humic acid and protein) on colloid transport in porous media were investigated with column experiments and numerical modeling. Colloid deposition was explored in double-pulse experiments (DPEs) by injecting ...
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Journal articleWater research · August 2013
Silver nanoparticles (AgNPs)-alginate composite beads were synthesized using three different approaches as filler materials of packed columns for simultaneous filtration-disinfection as an alternative portable water treatment process. The prepared composit ...
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Journal articleArchives of environmental contamination and toxicology · August 2013
Engineered cerium oxide nanoparticles (CeO2 NPs) are widely used in biomedical and engineering manufacturing industries. Previous research has shown the ability of CeO2 NPs to act as a redox catalyst, suggesting potential to both induce and alleviate oxida ...
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Journal articleNanotoxicology · June 2013
We describe a comprehensive optimisation study culminating in a standardised and validated approach for the preparation of titanium dioxide (TiO₂) nanoparticle dispersions in relevant biological media. This study utilises a TiO₂ reference nanomaterial base ...
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Journal articleScience of the Total Environment · April 1, 2013
Wastewater effluent and sewage sludge are predicted to be important release pathways for nanomaterials used in many consumer products. The uncertainty and variability of potential nanomaterial inputs, nanomaterial properties, and the operation of the waste ...
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Journal articleEnvironmental science & technology · March 2013
Electrically conductive polymer-nanocomposite (ECPNC) tight nanofiltration (NF) thin film membranes were demonstrated to have biofilm-preventing capabilities under extreme bacteria and organic material loadings. A simple route to the creation and applicati ...
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Journal articleEnvironmental science & technology · March 2013
Column experiments were conducted to investigate the transport of aqueous C60 (aqu-nC60), fullerol, silver nanoparticles (NPs) coated with polyvinylpyrrolidone (Ag-PVP) and stabilized by citrate (Ag-CIT) in biofilm-laden porous media. Gram-negative Pseudom ...
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Journal articleEnvironmental science & technology · February 2013
As the use of engineered nanomaterials becomes more prevalent, the likelihood of unintended exposure to these materials also increases. Given the current scarcity of experimental data regarding fate, transport, and bioavailability, determining potential en ...
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Journal articleEnvironmental science & technology · January 2013
Nanomaterials are highly dynamic in biological and environmental media. A critical need for advancing environmental health and safety research for nanomaterials is to identify physical and chemical transformations that affect the nanomaterial properties an ...
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Journal articleWater science and technology : a journal of the International Association on Water Pollution Research · January 2013
Carbon nanomaterials have been proposed as a basis for developing new technologies for photocatalytic oxidation and disinfection, improved membrane processes, adsorbents, and biofilm-resistant surfaces. This study details recent progress towards the develo ...
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Journal articleWater Quality Technology Conference and Exposition 2012 · December 1, 2012
A significant potential for nanoparticle incorporation into water treatment applications has focused on bacteria and virus inactivation due to singlet oxygen generation. Photosensitization of hydrophilic fullerenes generates singlet oxygen (1O
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Journal articleEnvironmental science & technology · December 2012
Theoretical and experimental approaches were employed to study the effect of aggregation on the affinity between nanoparticles (NPs) and a flat surface that is quantified by the attachment efficiency. Computer simulations were used to generate virtual aggr ...
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Journal articleEcotoxicology (London, England) · October 2012
Given the demonstrated antimicrobial properties of silver nanoparticles (AgNPs), and the key role that microorganisms play in performing critical ecosystem functions such as decomposition and nutrient cycling, there is growing concern that AgNP pollution m ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · October 2012
A theoretical investigation was conducted upon the steric interaction between a spherical particle and a flat plate. The effects of curvature on both the segment density distribution of polymer and on the steric interaction energy between a particle and a ...
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Journal articleJournal of Membrane Science · October 1, 2012
Electrically conductive polymeric ultrafiltration membranes were fabricated by pressure filtering a thin layer of poly(vinyl alcohol) - cross-linked with carboxylated multiwalled carbon nanotubes (CNTs) and succinic acid - onto a support membrane. The effe ...
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Journal articleChemical Engineering Journal · September 15, 2012
Fuel cell technology has drawn much attention from scientists and engineers due to its high energy conversion efficiency, quick start-up in the beginning of operation, portability, and minimal pollution. Proton exchange membranes (PEMs) play an important r ...
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Journal articleAquatic toxicology (Amsterdam, Netherlands) · September 2012
Silver nanoparticles (AgNPs) with antimicrobial properties are perhaps the most deployed engineered nanomaterials in consumer products. Almost all AgNPs are coated with organic materials to enhance their dispersion in water. Contributions of coatings to th ...
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Journal articleEnvironmental science & technology · September 2012
We introduce a novel methodology based on hyperspectral imagery with enhanced Darkfield microscopy for detection, characterization, and analysis of engineered nanoparticles in both ultrapure water and in complex waters, such as simulated-wetland ecosystem ...
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Journal articleWater research · September 2012
The effects of naturally occurring macromolecules such as humic acid (HA) and electrolytes on four fullerene nanoparticle suspensions (i.e., C(60), C(60)(OH)(24), single- and multiwall carbon nanotubes) were explored with respect to: (1) characteristics of ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · July 2012
The scaling of electrical double layer interaction energy from a plate-plate system to a sphere-plate system was reexamined, and it was found that accurate scaling without resorting to the Derjaguin approximation theoretically predicts the destabilization ...
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Journal articleEnvironmental science & technology · July 2012
Aggregation of photocatalytic semiconductors was determined to reduce the generation of free hydroxyl radicals in aqueous suspensions in a fashion dependent on aggregate size and structure. Static light scattering measurements were used to follow temporal ...
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Journal articleDesalination · June 15, 2012
Fouling continues to be an important limitation in membrane operation for water treatment. In this work, we compare various chemical agents with respect to their ability to remove fouling as well as their potential to deteriorate membrane rejection or the ...
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Journal articleThe Science of the total environment · June 2012
We describe the use of Bayesian networks as a tool for nanomaterial risk forecasting and develop a baseline probabilistic model that incorporates nanoparticle specific characteristics and environmental parameters, along with elements of exposure potential, ...
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Journal articleEnvironmental science & technology · June 2012
Inactivation rates of the MS2 bacteriophage and (1)O(2) generation rates by four different photosensitized aqueous fullerene suspensions were in the same order: aqu-nC(60) < C(60)(OH)(6) ≈ C(60)(OH)(24) < C(60)(NH(2))(6). Alterations to capsid protein seco ...
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Journal articleChemical Engineering Journal · May 15, 2012
An extension of Derjaguin-Landau-Verwey-Overbeek (DLVO) theory was developed to model the potential energy of interaction between a soft particle (particle coated with either uncharged polymer or polyelectrolyte) and a rigid flat surface prior to the parti ...
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Journal articleJournal of hazardous materials · May 2012
The surface chemistry of nanoparticles, including their hydrophobicity, is a key determinant of their fate, transport and toxicity. Engineered NPs often have surface coatings that control the surface chemistry of NPs and may dominate the effects of the nan ...
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Journal articleEnvironmental science & technology · April 2012
Transformations and long-term fate of engineered nanomaterials must be measured in realistic complex natural systems to accurately assess the risks that they may pose. Here, we determine the long-term behavior of poly(vinylpyrrolidone)-coated silver nanopa ...
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Journal articleThromb Haemost · April 2012
Recent studies have shown that ultra-large complexes (ULCs) of platelet factor 4 (PF4) and heparin (H) play an essential role in the pathogenesis of heparin-induced thrombocytopenia (HIT), an immune-mediated disorder caused by PF4/H antibodies. Because ant ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · March 2012
The propensity of silver nanoparticles (AgNPs) having two different polymer coatings (poly(vinylpyrrolidone), PVP, or gum arabic, GA) to aggregate, or to deposit to a reference surface (silica), was explored as a basis for differentiating the effect of sur ...
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Journal articleEnvironmental Engineering Science · February 1, 2012
A composite membrane composed of iron oxide and polyvinyl alcohol (PVA) was investigated as an alternative electrolyte material for proton exchange membranes (PEMs) in fuel cells using hydrogen as a fuel. Acetic acid (AA)-stabilized lepidocrocite (γ-FeOOH) ...
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Journal articleNanotoxicology · December 2011
Studies designed to investigate the environmental or biological interactions of nanoscale materials frequently rely on the use of ultrasound (sonication) to prepare test suspensions. However, the inconsistent application of ultrasonic treatment across labo ...
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Journal articleACS nano · November 2011
A wide variety of nanomaterials can be found naturally occurring in the environment, although finding and characterizing these materials remains a challenge due to their size. Recent studies in the field have shown that natural nanomaterials are common in ...
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Journal articleJournal of Nanoparticle Research · October 1, 2011
Nanomaterials such as fullerene C60, carbon nanotubes (CNTs), and other fullerenes show unique electrical, chemical, mechanical, and thermal properties that are not well understood in the context of the environmental behavior of this class of ca ...
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Journal articleComptes Rendus Physique · September 1, 2011
Nanomaterials exhibit novel properties that enable new applications ranging from molecular electronics to energy production. Proactive consideration of the potential impacts on human health and the environment resulting from nanomaterial production and use ...
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Journal articlePhysica Status Solidi Rapid Research Letters · September 1, 2011
While significant advances in our understanding of the behavior of engineered nanoparticles in the environment continue, there remains a need to engage the nanoparticle research community directly in the development and evaluation of environmentally benign ...
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Journal articleJournal of Nanoparticle Research · July 1, 2011
The International Alliance for NanoEHS Harmonization (IANH) organises interlaboratory comparisons of methods used to study the potential biological impacts of nanomaterials. The aim of IANH is to identify and reduce or remove sources of variability and irr ...
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Journal articleEnvironmental science & technology · June 2011
The transport of uncoated silver nanoparticles (AgNPs) in a porous medium composed of silica glass beads modified with a partial coverage of iron oxide (hematite) was studied and compared to that in a porous medium composed of unmodified glass beads (GB). ...
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Journal articleChemical Engineering Journal · June 1, 2011
With the increasing production and use of fullerene nanomaterials, it is imperative that quantitative analytical methods be developed to study their occurrence and behavior in the natural environment so that the risks posed by these materials to ecosystem ...
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Journal articleDesalination · May 3, 2011
Multi-wall carbon nanotube (MWCNT)/aromatic polyamide (PA) nanocomposite membranes were synthesized by a polymer grafting process. Surface morphology, roughness, and mechanical strength of the resultant nanocomposite membranes were characterized by scannin ...
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Journal articleEnvironmental science & technology · April 2011
The magnitude of engineered nanomaterials (ENMs) being produced and potentially released to the environment is a crucial and thus far unknown input to exposure assessment. This work estimates upper and lower bound annual United States production quantities ...
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Journal articleJournal of Physical Chemistry C · March 24, 2011
The environmental and health impacts of nanomaterials are becoming important topics of research in recent years. The unique advantages offered by these nanomaterials in wide range of applications cannot be realized until these concerns are resolved. Among ...
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Journal articleEnvironmental science & technology · March 2011
Silver nanoparticles (AgNPs) are increasingly used as antimicrobial additives in consumer products and may have adverse impacts on organisms when they inadvertently enter ecosystems. This study investigated the uptake and toxicity of AgNPs to the common gr ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · February 2011
Aggregation of uncoated ZnS nanoparticles was determined to have an unexpected impact on the particle's photoluminescent properties. Aggregation had significant consequences to both band-edge and trap-site photoluminescence, increasing the former and decre ...
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Journal articleEnvironmental health perspectives · January 2011
BackgroundThis commentary evolved from a workshop sponsored by the National Institute of Environmental Health Sciences titled "Superfund Contaminants: The Next Generation" held in Tucson, Arizona, in August 2009. All the authors were workshop part ...
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Journal articleJournal American Water Works Association · January 1, 2011
The objective of this work was to provide an in-depth analysis of the particulate composition of influent and effluent streams for granular media filters at full-scale water treatment plants. Findings from these analyses were evaluated with respect to the ...
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Journal articleAltex · 2011
In October 2010, a group of experts met as part of the transatlantic think tank for toxicology (t 4) to exchange ideas about the current status and future of safety testing of nanomaterials. At present, there is no widely accepted path forward to assure ap ...
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Journal articleWater research · January 2011
Fullerene nanomaterials are finding an increasing number of applications in energy and environmental technologies. However, substantial production and use of fullerenes will likely lead to environmental exposure with unknown consequences. In this study, aq ...
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Journal articleALTEX · January 2011
In October 2010, a group of experts met as part of the transatlantic think tank for toxicology (t4) to exchange ideas about the current status and future of safety testing of nanomaterials. At present, there is no widely accepted path forward to assure app ...
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Journal articleBlood · December 23, 2010
The immune response in heparin-induced thrombocytopenia is initiated by and directed to large multimolecular complexes of platelet factor 4 (PF4) and heparin (H). We have previously shown that PF4:H multimolecular complexes assemble through electrostatic i ...
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Journal articleJournal of environmental quality · November 2010
The release of engineered nanomaterials (ENMs) into the biosphere will increase as industries find new and useful ways to utilize these materials. Scientists and engineers are beginning to assess the material properties that determine the fate, transport, ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · November 2010
Exact, closed-form analytical expressions are presented for evaluating the potential energy of electrical double layer (EDL) interactions between a sphere and an infinite flat plate for three different types of interactions: constant potential, constant ch ...
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Journal articleEnvironmental Engineering Science · September 1, 2010
Numerous commercial products incorporate novel engineered nanomaterials such as gold, silica, zinc oxide, and fullerenes in complex matrices such as polymer composites, creams, and textiles. Analytical methods for detecting nanomaterials in complex matrice ...
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Journal articleACS nano · September 2010
Properties of nanomaterial suspensions are typically summarized by average values for the purposes of characterizing these materials and interpreting experimental results. We show in this work that the heterogeneity in aqueous suspensions of fullerene C(60 ...
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Journal articleNanomedicine (London, England) · August 2010
Nanomaterials and the technologies they enable are often presented as important innovations that will play a critical role in solving problems that range from energy, water and food supply to improved medical treatments. Ironically, many of the more 'media ...
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Journal articleLangmuir · July 6, 2010
Theory is developed that relates the reactivity of nanoparticles to the structure of aggregates they may form in suspensions. This theory is applied to consider the case of reactive oxygen species (ROS) generation by photosensitization of C60 fu ...
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Journal articleEnvironmental science & technology · July 2010
The possibility of simultaneous particle aggregation and deposition in a porous medium was examined for the case of TiO(2) nanoparticles (NPs). While potential for particle aggregation is typically assumed to be negligible in porous media due to favored in ...
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Journal articleJournal of colloid and interface science · June 2010
Particle aggregation is induced in derivatized fullerene (fullerol) suspensions by introducing different counter-ion species (Na(+) Ca(2+) and Mg(2+)) and concentrations. The suspensions are filtered through 20 nm ceramic membranes under different transmem ...
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Journal articleMacromolecular Reaction Engineering · June 1, 2010
Polymeric porous membranes were fabricated from templates made from silica particles. The templates were obtained by self-assembly and by the Langmuir-Blodgett (L-B) technique. For the self-assembly technique, suspensions of silica particles in ethanol wer ...
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Journal articleAquatic Toxicol · 2010
Silver nanoparticles (AgNPs) are frequently used as antimicrobials. While the mechanism(s) by which AgNPs are toxic are unclear, their increasing use raises the concern that release into the environment could lead to environmental toxicity. We characterize ...
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Journal articleWater science and technology : a journal of the International Association on Water Pollution Research · January 2010
A self-organized nano-structured, photocatalytic TiO₂ membrane with large surface area of anatase crystallites was successfully fabricated by anodization. The nano-structured anodized TiO₂ membrane was characterized using SEM, XRD and TEM techniques and th ...
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Journal article · December 1, 2009
This chapter details recent progress toward the development of the proposed applications. It examines the development of fullerene composite materials using CNTs to strengthen membranes and modify membrane surface chemistry. It explores the use of fulleren ...
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Journal articleLangmuir · October 6, 2009
The nature of fullerene-water interactions and the role that they play in the fate of C60 in aqueous systems is poorly understood. This work provides spectroscopic evidence for the surface hydroxylation of the initially hydrophobic C60
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Journal articleNature nanotechnology · October 2009
The regulation of engineered nanoparticles requires a widely agreed definition of such particles. Nanoparticles are routinely defined as particles with sizes between about 1 and 100 nm that show properties that are not found in bulk samples of the same mat ...
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Journal articleEnvironmental science & technology · September 2009
Determining the fate and interactions of nanomaterials in complex environmental contexts is required to assess exposure and possible harm as well as to inform regulation. As the nanotechnology industry moves up into the rarified air of trillion dollar econ ...
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Journal articleEnvironmental science & technology · September 2009
Nonenveloped viruses are shown to be inactivated by singlet oxygen ((1)O2) produced in UVA photosensitized aqueous suspensions of a polyhydroxylated fullerene (C60(OH)22-24; fullerol, 40 microM). Experiments were performed with MS2, a ssRNA bacteriophage, ...
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Journal articleASEE Annual Conference and Exposition, Conference Proceedings · September 1, 2009
The Partnership for Education and Research in Membrane Nanotechnologies (PERMEANT) is an NSF PIRE project involving Michigan State University (USA), Duke University (USA), Kyiv-Mohyla Academy (Ukraine), Université Paul Sabatier (France), Centre Européen de ...
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Journal articleActualite Chimique · August 10, 2009
Membranes, which are used commercially for the last 50 years, are more and more employed since the last ten years. They can be used at the industrial level for liquid, solid or gaseous separations down to the microscopic scale. In spite of all the advantag ...
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Journal articleEnvironmental science & technology · August 2009
Ultraviolet (UV) irradiated polyhydroxylated fullerene (fullerol) nanomaterials are examined for their potential to degrade organic compounds via reactive oxygen species (ROS) mediated by a photosensitization process. Organic compounds were selected for th ...
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Journal articleEnvironmental science & technology · August 2009
C60 fullerene is a promising material because of its unique physiochemical properties. However, previous studies have reported that colloidal aggregates of C60 (nC60) produce toxicity in fish and human cell cultures. The preparation method of nC60 raises q ...
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Journal articleEnvironmental science & technology · June 2009
An upper bound is estimated for the magnitude of potential exposure to nano-TiO2 with the purpose of enabling exposure assessment and, ultimately, risk assessment Knowledge of the existing bulk TiO2 market is combined with available nano-TiO2 production da ...
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Journal articleEnvironmental science & technology · June 2009
The production of reactive oxygen species (ROS) by aqueous suspensions of fullerenes and nano-TiO2 (Degussa P25) was measured both in ultrapure water and in minimal Davis (MD) microbial growth medium. Fullerol (hydroxylated C60) produced singlet oxygen (1O ...
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Journal articleNanotoxicology · June 1, 2009
Cerium dioxide nanoparticles have been proposed for an increasing number of applications in biomedicine, cosmetic, as polishing materials and also as byproducts from automotive fuel additives. The aim of this study was to examine the potential in vitro cyt ...
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Journal articleEnvironmental pollution (Barking, Essex : 1987) · April 2009
The level of production of nanoparticles will inevitably lead to their appearance in air, water, soils, and organisms. A theoretical framework that relates properties of nanoparticles to their biological effects is needed to identify possible risks to huma ...
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Journal articleJournal of Membrane Science · April 1, 2009
The objective of this research was to evaluate a select number of promising surface treatments for making ceramic membranes hydrophobic and suitable for application in direct contact membrane distillation (DCMD). Alumina anodisc™ membranes were made hydrop ...
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Journal articleEnvironmental pollution (Barking, Essex : 1987) · April 2009
In this paper, we show that concentrations of manufactured carbon-based nanoparticles (MCNPs) in aquatic sediments will be negligible compared to levels of black carbon nanoparticles (BCNPs). This is concluded from model calculations accounting for MCNP se ...
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Journal articleJournal of Membrane Science · March 5, 2009
The attachment and respiratory activity of the model bacterium, Escherichia coli K12 on microfiltration (MF) membranes coated with the fullerene C60 and the influence of colloidal aggregates of C60 (nC60) on this bacterium ...
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Journal articleActualite Chimique · 2009
Membranes, which are used commercially for the last 50 years, are more and more employed since the last ten years. They can be used at the industrial level for liquid, solid or gaseous separations down to the microscopic scale. In spite of all the advantag ...
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Journal articleEnvironmental science & technology · September 2008
Iron-based nanoparticles have been proposed for an increasing number of biomedical or environmental applications although in vitro toxicity has been observed. The aim of this study was to understand the relationship between the redox state of iron-based na ...
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Journal articleFuel Cells Bulletin · August 1, 2008
Ceramic membranes derived from carboxylate-ferroxane nanoparticles are shown to yield high power (5.21 mW/cm2) and current (16.5 mA/cm2) densities in a working membrane-electrode assembly, comparable to those obtained using untreated ...
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Journal articleJournal of Membrane Science · June 20, 2008
Ceramic membranes derived from carboxylate-ferroxane nanoparticles are shown to yield high power (5.21 mW cm-2) and current (16.5 mA cm-2) densities in a working membrane electrode assembly, comparable to those obtained using untreate ...
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Journal articleEnvironmental science & technology · June 2008
Buckminsterfullerene (C60) is a known photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties in aqueous environments are still not well understood or modeled. In this study, production of both singlet ...
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Journal articleEnvironmental Engineering Science · May 1, 2008
Carbon nanotubes exhibit superior mechanical and electrical properties that make them attractive for developing new composite materials. In this research, we examined the properties of ultrafiltration membranes made from carbon nanotube/polymer composites. ...
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Journal articleNano letters · May 2008
The cytotoxic and antibacterial properties of nC 60, a buckminsterfullerene water suspension, have been attributed to photocatalytically generated reactive oxygen species (ROS). However, in this work, neither ROS production nor ROS-mediated damage is found ...
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Journal articleJournal of Membrane Science · April 10, 2008
In this paper, vertical scanning interferometer (VSI) is used to analyze the decrease in cake layer height of membranes. Nanofiltration membrane was fouled with CaCl2 and humic acid solution for 24 h and then, put into cleaning solution to disso ...
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Journal articleLangmuir : the ACS journal of surfaces and colloids · April 2008
When normalized per unit of surface area, the quantity of arsenic adsorbed at the maghemite surface remains constant for particles between 300 and 20 nm. However, nanoparticles smaller than 20 nm exhibit enhanced adsorption capacity. The origin of this obs ...
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Journal articleJournal of Membrane Science · February 15, 2008
The removal of several hormones and antibiotics by nanofiltration membranes was studied in mixed solutions. The effects of solution chemistry, organic matter and salinity were investigated on the rejection of tetracycline's and sulfanamides and selected ho ...
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Journal articleWater science and technology : a journal of the International Association on Water Pollution Research · January 2008
An assessment of the potential risks posed by nanomaterials will require case-by-case evaluations of the processes controlling exposure and hazards such as toxicity. Factors that control fullerene transport and transformation in aqueous environments and th ...
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Journal articleBlood · December 15, 2007
Heparin-induced thrombocytopenia (HIT) is an antibody-mediated disorder that occurs with variable frequency in patients exposed to heparin. HIT antibodies preferentially recognize large macromolecular complexes formed between PF4 and heparin over a narrow ...
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Journal articleJournal of Membrane Science · December 1, 2007
An iron-based ceramic material is shown to have favorable properties as an electrolyte material for proton exchange membranes in fuel cells. Iron (ferroxane) and aluminum (alumoxane) metal-oxane nanoparticles were prepared as precursor materials for membra ...
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Journal articleEnvironmental science & technology · November 2007
The physical-chemical behavior of the fullerene C60 in environmental and physiological media is of interest for understanding the potential transport, exposure, and impacts of these materials on organisms and ecosystems. We considerthe role of electrolyte ...
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Journal articleJournal of colloid and interface science · October 2007
Here we report on the characteristics of fullerol in aqueous systems and examine those conditions that affect the physical state of fullerol in water. When dispersed in water fullerol forms polydisperse suspensions characterized by both small ( approximate ...
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Journal articleEnvironmental science & technology · September 2007
The production of two reactive oxygen species through UV photosensitization of polyhydroxylated fullerene (fullerol) is shown to enhance viral inactivation rates. The production of both singlet oxygen and superoxide by fullerol in the presence of UV light ...
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Journal articleEnvironmental Engineering Science · May 21, 2007
Morphological variations of precipitated salts on nanofiltration (NF) and reverse osmosis (RO) membranes were compared for conditions where naturally occurring differences in feedwater composition, sometimes coupled with differences in hydrodynamics, produ ...
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Journal articleEnvironmental science & technology · April 2007
Several fullerene-based nanomaterials generate reactive oxygen species that can damage cells. In this study, we investigated the effect of buckminsterfullerene (C60) introduced as colloidal aggregates in water (nC60) on bacterial membrane lipid composition ...
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Journal articleFullerenes Nanotubes and Carbon Nanostructures · December 1, 2006
In this work, we have studied the affinity of pure C 60 fullerenes with water. Although C 60 have always been known as hydrophobic particles, we show that this characteristic does not remain when contact between C 60 and H 2 O is forced by mechanical stirr ...
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Journal articleDesalination · October 2, 2006
A batch, dead-end filtration method is used to compare the effect of various pretreatment operations on membrane performance. The dead-end method is compared with results obtained in cross-flow filtration as well as withconventional SDI measurements. Dead- ...
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Journal articleIntegrated environmental assessment and management · October 2006
In the environmental technology industry alone, nanomaterials will enable new means of reducing the production of industrial wastes, using resources more sparingly, remediating industrial contamination, providing potable water, and improving the efficiency ...
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Journal articleNano letters · August 2006
Nanomaterial properties differ from those bulk materials of the same composition, allowing them to execute novel activities. A possible downside of these capabilities is harmful interactions with biological systems, with the potential to generate toxicity. ...
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Journal articleJournal of Membrane Science · July 5, 2006
In this paper, vertical scanning interferometry (VSI) and atomic force microscopy (AFM) were used to characterize the topography of several nanofiltration and reverse osmosis membrane surfaces. Comparing roughness results from the two different characteriz ...
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Journal articleEnvironmental science & technology · July 2006
Although the current production of oxide nanoparticles may be modest, the wide range of proposed applications and forecasted growth in production has raised questions about the potential impact of these nanoparticles on the environment and human health. Ir ...
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Journal articleLangmuir · April 11, 2006
We examined the physical and chemical characteristics of colloidal dispersions of fullerene materials (nC 60) produced through several solvent exchange processes and through extended mixing in water only. The nC 60 produced via the di ...
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Journal articleWater science and technology : a journal of the International Association on Water Pollution Research · January 2006
Emerging technologies, including nanotechnologies, affect the social, economic, and environmental dimensions of our world, often in ways that are entirely unanticipated. There is considerable effort underway to explore uses of nanomaterials in applications ...
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Journal articleJournal of Membrane Science · December 1, 2005
This work considers the hypothesis that the association of trace-level hydrophobic organic compounds with dissolved organic matter (DOM), similar to macromolecular materials found in natural water systems, may influence the contaminant's ability to permeat ...
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Journal articleACS Division of Environmental Chemistry Preprints of Extended Abstracts · December 1, 2005
Iron oxide nanoparticles (ferroxane) and aluminum oxide nanoparticles (alumoxane) were synthesized via an environmentally benign process, alternative to sol-gel process, for direct methanol fuel cell. For both oxane materials, the conductivity improved as ...
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Journal articleACS National Meeting Book of Abstracts · December 1, 2005
An iron-based ceramic material is a good candidate as membrane material for PEMFC with conductivities ranging from 1.5 to 2.5 × 10-2 S/cm at 58-100% RH. These membranes have comparable conductivity to the Nafion membrane with the advantages of l ...
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Journal articleACS Division of Environmental Chemistry Preprints of Extended Abstracts · December 1, 2005
Several types of nC60 manufactured through four different, but established preparation techniques, i.e., solvent exchange using tetrahydrofuran (THF) and water (THF/nC60; solvent exchange using toluene, acetone, THF and water (TTA/nC< ...
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Journal articleEnvironmental science & technology · November 2005
A relative risk assessment is presented for the industrial fabrication of several nanomaterials. The production processes for five nanomaterials were selected for this analysis, based on their current or near-term potential for large-scale production and c ...
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Journal articleJournal of Nanoparticle Research · October 1, 2005
The propensity of n-C60 to aggregate and deposit will play a key role in determining its longevity in aquatic systems, and therefore the potential exposure and risk presented by these colloids. We consider the origin of n-C60 stabilit ...
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Journal articleEnvironmental science & technology · September 2005
In this study we report on the electrokinetic behavior of colloidal aggregates of C60fullerenes (n-C60) produced through two different techniques: solvent exchange and extended mixing with water. In the first technique, used to produce colloidal materials ...
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Journal articleEnvironmental Engineering Science · September 1, 2005
Formulations of bentonite-cement composites are explored as a basis for creating a range of structured, semipermeable layers adapted to in situ capping of contaminated underwater sediments. In addition to being mechanically stable, such composites allow fo ...
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Journal articleJournal of Colloid and Interface Science · March 15, 2005
Porous solids were obtained from self-assembled deposits of silica particles used as templates to form 3-D porous membranes. The effect of the solvent chemistry on the morphology of the deposits was investigated. The parameters of interest are surface tens ...
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Journal articleEnvironmental science & technology · March 2005
The relative production rate of reactive oxygen in aqueous solution sensitized by fullerol (a polyhydroxylated, water-soluble form of the fullerene C60) was measured and compared to known reactive oxygen sensitizers using an oxygen consumption method. The ...
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Journal articleWater science and technology : a journal of the International Association on Water Pollution Research · January 2005
The processes that control particle deposition on surfaces that are of interest in understanding operational aspects of membrane filtration, also hold significance in controlling the morphology of particle deposits as intermediate steps in membrane fabrica ...
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Journal articleAiche Annual Meeting Conference Proceedings · December 1, 2004
Formulations of bentonite-cement composites are explored as a basis for creating a range of structured, semipermeable layers adapted to in situ capping of contaminated underwater sediments. In addition to being mechanically stable, such composites provide ...
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Journal articleAiche Annual Meeting Conference Proceedings · December 1, 2004
Silver nanoparticle deposition from suspension is proposed as a route for the morphological design of controllably disordered self-affine substrates for surface-enhanced Raman sensing of water pollutants. Ionic strength is used as a variable parameter to c ...
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Journal articleEnvironmental science & technology · October 2004
The production of significant quantities of engineered nanomaterials will inevitably result in the introduction of these materials to the environment. Mobility in a well-defined porous medium was evaluated for eight particulate products of nanochemistry to ...
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Journal articleJournal of Membrane Science · September 15, 2004
The structure of membrane cakes formed in cross-flow filtration was investigated for conditions of variable particle size and solution ionic strength. In all cases, microscopic examination of membrane cake cross-sections revealed a stratified structure: a ...
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Journal articleEnvironmental science & technology · August 2004
Products of nanochemistry have been proposed in a number of applications ranging from soil stabilization and cosmetics to groundwater remediation. A fundamental understanding of the transport properties of these materials is essential to assess their effic ...
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Journal articleWater research · January 2004
In this paper, factors influencing the flux decline of nanofiltration membranes for the treatment of dye bath wastewaters were investigated. Experiments were performed with synthetic wastewaters. Synthetic solutions were prepared in different dye and salt ...
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Journal articleAIChE Annual Meeting, Conference Proceedings · 2004
Silver nanoparticle deposition from suspension is proposed as a route for the morphological design of controllably disordered self-affine substrates for surface-enhanced Raman sensing of water pollutants. Ionic strength is used as a variable parameter to c ...
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Journal articleJournal of Membrane Science · December 15, 2003
Ferroxane nanoparticles, obtained from reaction of lepidocrocite (FeOOH) and acetic acid at room temperature, were applied to the fabrication of ceramic membranes. The size of the nanoparticles and the kinetics of the reaction were investigated. Ferroxane ...
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Journal articleJournal of Membrane Science · October 15, 2003
The fabrication of alumina ultrafiltration membranes using acetic acid surface stabilized alumina nanoparticles (A-alumoxanes) has been investigated. The pore size, pore size distribution, and molecular weight cut-off (MWCO) parameters of the resulting mem ...
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Journal articleMaterials Research Society Symposium Proceedings · July 25, 2003
Porous solids were obtained from self-assembled deposits of silica nanoparticles used as templates to form 3-D porous membranes. The effect of the solvent chemistry on the morphology of the deposits was investigated. The parameters of interest are surface ...
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Journal articleChemical Engineering Science · January 1, 2003
Scaled-down models of industrial filtration units are often used in laboratory studies of membrane processes. Knowledge of the flow field and shear stresses at the membrane surface is vital for the accurate interpretation of bench scale experiments. In thi ...
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Journal articleEnvironmental Engineering Science · January 1, 2003
A Computational Fluid Dynamic (CFD) tool was used to evaluate the role of aggregate porosity on aggregate collisions due to differential sedimentation. This modeling study shows the influence of the hydrodynamics of porous aggregates on the rectilinear agg ...
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Journal articleMaterials Research Society Symposium Proceedings · January 1, 2003
Ferroxane nanoparticles are precursors to iron oxide ceramic porous membranes. The ferroxane-derived ceramics have an average pore size of 24 nm and a surface area of 80 m2/g. Previous work has shown that these membranes have a molecular weight ...
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Journal articleJournal of Colloid and Interface Science · December 15, 2002
The morphology of fouling layers is an important factor in modeling permeate flux behavior in membrane filtration. In the present paper, the relationship between the chemical composition of suspension and the morphological properties of the deposit formed ...
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Journal articleLangmuir · June 12, 2002
Tricalcium silicate (C3S), the major phase of cement-based materials, contains naturally a few hundred parts per million of heavy metals. An X-ray absorption spectroscopy (XAS) study at the Zn K-edge has been carried out to elucidate the binding ...
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Journal articleChemistry of Materials · March 19, 2002
A new environmentally benign process for producing Fe-based ceramics of variable properties is presented. We have demonstrated that the reaction between lepidocrocite and acetic acid (=AA) in water results in the formation of carboxylate-FeOOH nanoparticle ...
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Journal articleEnvironmental Engineering Science · January 1, 2002
A series of membrane filtration experiments was carried out in a crossflow flat slit geometry to study permeate flux dependence on particle size and operational mode. Dilute monodisperse suspensions of polystyrene particles 20, 50, 100, and 680 nm in diame ...
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Journal articleJournal of Membrane Science · January 1, 2002
Alumoxanes nanoparticles were cast onto α-alumina supports by slip-coating to develop asymmetric ultrafiltration ceramic membranes. Membrane layers as thin as 1 or 2μm were achieved. The effect of sintering conditions was investigated. Membrane surface mor ...
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Journal articleEnvironmental science & technology · December 2001
We are evaluating strontium isotopes as alternative tracers of landfill leachate in groundwater. The municipal landfill studied here is located in southeastern France. This landfill has no bottom liner, and wastes are placed directly on the ground. Based o ...
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Journal articleJournal of Membrane Science · November 15, 2001
The fabrication of asymmetric alumina ultrafiltration membranes using acetic acid surface stabilized alumina nanoparticles (A-alumoxanes) has been investigated. Contacting α-alumina supports with an aqueous solution of A-alumoxane (after firing to 1000°C) ...
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Journal articleJournal of Colloid and Interface Science · November 1, 2001
Aggregate structure, i.e., fractal dimension, has a coupled geometric and hydrodynamic impact on the aggregate collision frequencies. In this work, we evaluated different collision frequency kernel calculation schemes to simulate experimentally determined ...
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Journal articleJournal of Environmental Engineering · June 1, 2001
An approach is presented for the numerical optimization of low-pressure membrane filtration processes. A multidimensional optimization of an ultrafiltration system is formulated for cost minimization and numerically solved for key optimal design and operat ...
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Journal articleJournal of Colloid and Interface Science · May 1, 2001
The effect of the collision efficiency of particles deposited onto a rough substrate and the evolution of the deposit profile were investigated using 2D on-lattice Monte Carlo simulations. The case of a diffusive long-range transport regime as representati ...
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Journal articleWater Science and Technology Water Supply · January 1, 2001
An extended model integrating several particle back-transport theories has been proposed by Sethi and Wiesner to predict transient permeate flux as a function of operational parameters for constant permeate flux (CF) and constant transmembrane pressure (CP ...
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Journal articleJournal of Environmental Engineering · 2001
An approach is presented for the numerical optimization of low-pressure membrane filtration processes. A multidimensional optimization of an ultrafiltration system is formulated for cost minimization and numerically solved for key optimal design and operat ...
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Journal articleJournal of Membrane Science · August 15, 2000
Atomic force microscopy, nitrogen adsorption-desorption, and measurements of intrinsic permeability are used to characterize ceramic membranes made using a newly developed alumoxane-based method conceived as an environmentally benign process. AFM, BET and ...
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Journal articleWater Research · June 15, 2000
Treatment costs and cost effectiveness of a hollow-fiber nanofiltration (HFNF) system vs. an integrated system comprised of spiral-wound nanofiltration (SWNF) pre-treated with hollow-fiber ultrafiltration (HFUF) are estimated and compared using numerical s ...
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Journal articleJournal of Membrane Science · January 17, 2000
For given values of the flow rate and RPM, stationary membrane disk filters require less power input. Rotating membrane disk filters produce a higher shear stress on the membrane surface which may reduce fouling but may also result in a reversed flow of pe ...
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Journal articleWater Research · January 1, 2000
Fouling of rotating disk membranes as function of operating conditions and feed suspension characteristics was investigated in a series of laboratory experiments. A single-disk laboratory unit was operated over a range of disk rotation speeds and permeatio ...
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Journal articleEnvironmental Engineering Science · January 1, 2000
A model is presented for estimating costs of crossflow ultrafiltration and microfiltration processes. The model incorporates separate correlations for several major components of capital costs, thus accounting for different economies of scale associated wi ...
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Journal articleJournal of Environmental Engineering · December 1, 1999
The premise that the morphology of deposits formed from colloids, aerosols, and other particulate materials can be predicted from their transport properties and surface chemistries is explored. Universality classes that group the conditions of particles in ...
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Journal articleEnvironmental Science and Technology · March 15, 1999
The composition and morphology of colloidal materials entering an urban waterway (Brays Bayou, Houston, U.S.A.) during a storm event was investigated. Analyses of organic carbon, Si, Al, Fe, Cr, Cu, Mn, Zn, Ca, Mg, and Ba were performed on the fraction of ...
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Journal articleChemical Engineering Journal · January 29, 1999
Computational fluid dynamics is used to investigate designs for rotating membrane disk filters. Simulations have been run for the case of water permeating through a membrane disk rotating in a pressurized housing. The water was assumed to be Newtonian, inc ...
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Journal articleJournal of Environmental Engineering · 1999
The premise that the morphology of deposits formed from colloids, aerosols, and other particulate materials can be predicted from their transport properties and surface chemistries is explored. Universality classes that group the conditions of particles in ...
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Journal articleJournal of Colloid and Interface Science · August 15, 1998
The fractal dimension of a particle aggregate can provide fundomental information on the structure and origin of the aggregate. The analysis of large chemically homogeneous fractal objects has been achieved, but reliable methods of estimating the fractal d ...
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Journal articleJournal American Water Works Association · June 1, 1998
Researchers are tackling issues related to larger modules and plants, pretreatment, permitting, and disposal of residuals. ...
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Journal articleEnvironmental Science and Technology · May 1, 1998
Power-law scaling of particle size distributions in air, water, and soil have been frequently reported and are sometimes interpreted in the context of a fractal dimension to yield estimates of the geometrical characteristics of particles and aggregates suc ...
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Journal articleEnvironmental Science and Technology · January 15, 1998
Contamination of surface and groundwaters by atrazine is a problem for water utilities in the United States and Europe. Though not removed by traditional liquid-solid separation, it is removed by nanofiltration. Retention of atrazine by a series of dialysi ...
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Journal articleJournal of Membrane Science · January 7, 1998
Specific flux data were obtained during the transient period of flux decline in laminar crossflow filtration. Effects of hydrodynamics on cake parameters such as specific resistance, mass and particle size distribution were studied experimentally. An evalu ...
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Journal articleWater Research · January 1, 1998
This work explores the role of the raw water matrix, particularly natural organic matter (NOM), in determining the removal of atrazine by nanofiltration membranes. The nature and relative concentration of NOM, the presence of calcium and ionic strength aff ...
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Journal articleJournal / American Water Works Association · 1998
Nanofiltration (NF) costs attributable to variations in chemical cleaning intervals (resulting from changes in permeate flux and feedwater recovery) were estimated based on membrane fouling rates, associated cleaning intervals, backwashing frequencies, per ...
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Journal articleJournal American Water Works Association · January 1, 1998
Nanofiltration (NF) costs attributable to variations in chemical cleaning intervals (resulting from changes in permeate flux and feedwater recovery) were estimated based on membrane fouling rates, associated cleaning intervals, backwashing frequencies, per ...
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Journal articleJournal of Membrane Science · December 10, 1997
Dominant mechanisms of particle transport in cross-flow membrane filtration are unified to obtain a generalized model for time-dependent permeate flux. The unified model extends an earlier model based on shear-induced diffusion and a concentrated flowing l ...
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Journal articleEnvironmental Science and Technology · October 1, 1997
Experimental observations of monodispersed latex particles filtered through a bed of spherical glass beads indicated that flow ram plays an important role in head loss development by influencing the morphology of the deposits as well as the deposit distrib ...
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Journal articleEnvironmental Science and Technology · March 1, 1997
Particle residence time distributions in a membrane channel are interpreted to elucidate mechanisms of particle transport end colloidal fouling in membrane filtration. A comparison of particle size distributions in the membrane feed suspensions and deposit ...
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Journal articleWater Environment Research · January 1, 1997
Produced water from gas and oil operations is purportedly the largest single source of waste generated in the U.S., with an annual production rate of more than 2.7 bil t (3 bil ton). Results are presented from bench-scale pilot tests of membrane ultrafiltr ...
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Journal articleJournal of Environmental Engineering · January 1, 1997
Water quality, metals concentration, and particle size distributions were characterized in urban runoff. The distribution of metals in the macrocolloidal (0.45-20 μm) and dissolved (<0.45 μm) size fractions was determined from samples taken under both stor ...
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Journal articleChemistry of Materials · January 1, 1997
The objective of our research is the development of an environmentally benign process for the fabrication of alumina-based ceramics. We have designed an alternative synthetic pathway to alumina ceramics that does not utilize toxic reagents or volatile orga ...
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Journal articleJournal of Colloid and Interface Science · January 15, 1996
Hydrodynamic properties of fractal aggregates with radially varying permeability are investigated in terms of two parameters: radius of equivalent solid sphere experiencing the same drag as the aggregate (Ω* radius of aggregate) and fluid collection effici ...
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Journal articleWater Environment Research · January 1, 1996
Effects of transmembrane pressure and membrane pore size on the microfiltration of oil-in-water emulsions are reported. A model for calculating the critical pressure required to force the entry of an oil drop into a membrane pore is formulated based on the ...
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Journal articleEnvironmental Science and Technology · January 1, 1996
The success of pump-and-treat or in situ remediation of contaminated aquifers depends in part on the ability to maintain the permeability of the aquifer, withdrawal wells, and delivery systems at a reasonable cost while moving significant quantities of wat ...
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Journal articleJournal of Environmental Engineering · 1995
Models describing permeate flux, rejection, and cost are coupled to evaluate the performance and cost of ultrafiltration as a function of raw-water quality. The model for permeate flux extends a previous model for colloidal fouling based on shear-induced d ...
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Journal articleJournal of Environmental Engineering United States · January 1, 1995
Models describing permeate flux, rejection, and cost are coupled to evaluate the performance and cost of ultrafiltration as a function of raw-water quality. The model for permeate flux extends a previous model for colloidal fouling based on shear-induced d ...
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Journal articleReviews in Chemical Engineering · January 1, 1995
A review of theoretical and experimental investigations of laminar fluid flow in porous ducts is presented. We extend the analysis of Terrill (1964) to derive similarity solutions for axial and lateral velocity profiles, pressure gradients and wall skin fr ...
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Journal articleJournal of Membrane Science · August 8, 1994
The effects of pH and ionic strength on the performance of ceramic microfiltration membranes are evaluated. An α-alumina membrane, characterized by a 0.8 μm nominal pore diameter, was operated in a crossflow configuration with three types of feed waters: p ...
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Journal articleJournal of Colloid and Interface Science · January 1, 1994
Monte Carlo simulations of colloid deposition on a one-dimensional permeable surface from a uniform flow field are reported. The effects of particle size, fluid velocity, and particle density on the transport of particles to the collector surface by fluid ...
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Journal articleJournal American Water Works Association · January 1, 1994
Cost of several ultrafiltration and nanofiltration processes are compared with the cost of conventional liquid-solid separation with or without GAC adsorption for small facilities. Data on raw-water quality, permeate flux, recovery, frequency of backflushi ...
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Journal articleJournal of Environmental Engineering United States · January 1, 1993
A model for capital and operating costs of low-pressure membrane filtration is presented. The model is used to explore the impact of variables describing system operation and membrane characteristics on treatment costs as well as to compare the cost of tre ...
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Journal articleWater Research · January 1, 1993
The disturbances in uniform creeping flow in the presence of an isolated porous floc are investigated theoretically. Using the Carman-Kozeny equation, the floc permeability is related to its fractal dimension, D. Fluid streamlines, drag coefficient and the ...
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Journal articleJournal of Environmental Engineering United States · January 1, 1993
Experimental work on the role of feed suspension polydispersivity on the performance of granular media filters is presented. Suspensions of latex particles of sizes 0.09 μm, 0.944 μm, 7.04 μm, and 7.6 um, and their paired combinations were filtered through ...
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Journal articleWater Environment Research · January 1, 1993
A theoretical description of single-phase flow through porous media having permeable boundaries is presented. The volume averaged momentum transfer equation is solved numerically by a finite difference technique after neglecting the nonlinear inertia term. ...
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Journal articleJournal of Engineering Mathematics · November 1, 1992
An approximate solution to the 2-D Navier-Stokes equations for steady, isothermal, incompressible, laminar flow in a channel bounded by one porous wall subject to uniform suction is derived. The solution is valid for small values of the Reynolds number bas ...
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Journal articleEnvironmental Science and Technology · August 1, 1992
Particle transport and deposition studies in laminar cross-flow membrane filtration are reported. Particle residence time distributions (RTDs) in experimental conditions typical of ultra- and microfiltration are compared with theoretical predictions incorp ...
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Journal articleWater Science and Technology · January 1, 1992
The effect of polymeric coagulant aids and the time of their addition relative to the addition of the primary metal coagulants was investigated in a series of jar tests. Solutions of humic acid were coagulated using iron and aluminum coagulants in conjunct ...
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Journal articleJournal American Water Works Association · January 1, 1992
Numerical simulations and experimental work for evaluating transport mechanisms for colloidal foulants in pressure-driven membrane systems are discussed. A model for concentration polarization is used to explore the role of ionic strength in determining th ...
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Journal articleWater Research · January 1, 1992
The growth of porous aggregates during initial mixing is investigated in a series of numerical simulations. Hydrodynamic radii of aggregates composed of i primary particles are used to calculate collision rate constants as a function of fractal dimension, ...
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Journal articleWater Science and Technology · January 1, 1992
Results from a pilot scale study on the performance of ceramic membranes in treating high turbid waters are presented. Coagulation pretreatment using alum or ferric sulfate was found to improve permeate quality and increase permeate flux. In comparison wit ...
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Journal articleJournal American Water Works Association · January 1, 1992
Membrane technology is a process that has not been widely used in potable water treatment, except for reverse osmosis applications. Because of increasingly stringent regulations, this technology is being examined for the potential application of ultrafiltr ...
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Journal articleWater Science and Technology · January 1, 1992
Particle transport in crossflow membrane filters is the result of complex interactions originating from module hydrodynamics, suspension chemistry and external forces. Experimental and theoretical investigations of particle transport in dilute suspensions ...
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Journal articleWater Research · January 1, 1992
Membrane fouling in crossflow microfiltration of coagulated synthetic raw water has been studied in order to evaluate the influence of aluminium coagulant in the filtration liquid-solid separation. The presence of small colloids leads to a fast fouling of ...
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Journal articleProceedings AWWA Annual Conference · December 1, 1991
The effect of particle polydispersivity in the influent suspension to granular media filters has been studied experimentally. Suspensions of spherical latex particles of sizes 0.09 μm, 0.944 μm and 7.04 μm were filtered through a porous bed of glass sphere ...
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Journal articleProceedings AWWA Annual Conference · December 1, 1991
Pressure-driven membrane processes include reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF) and microfiltration (MF). Inherent in all of these membrane separation processes is the accumulation of rejected materials near the membrane surface. ...
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Journal articleJournal of Hazardous Materials · January 1, 1991
The effects of hydraulic conductivity and injection velocity on microbial transport through porous media were investigated. Glass chromatography columns were packed separately with clean quartz sand of two diameters (0.368mm or 0.24O mm) and two hydraulic ...
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Journal articleJournal of Membrane Science · September 1, 1990
The fouling characteristics of dispersions of dissolved organic materials and colloids are investigated in a series of ultrafiltration experiments. Dispersions of tannic acid, humic acid and kaolin are filtered using a cross-flow hollow fiber module. In so ...
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Journal articleJournal American Water Works Association · January 1, 1989
The particle-removal performance of several full-scale water treatment plants is evaluated using a systems analysis approach. Sources of particle-volume concentration in raw water are discussed, and it is suggested that 'dissolved' organic materials in raw ...
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Journal articleJournal of Environmental Engineering United States · January 1, 1989
The deposition of small colloids or macromolecules in membrane pores and the subsequent irreversible fouling of the membrane is considered using a simple model for membrane fouling. As a strategy for avoiding pore fouling, it is proposed that foulants capa ...
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Journal articleJournal of Environmental Engineering United States · January 1, 1987
The identification of a least cost design and configuration of unit processes for particle removal in water treatment is formulated as a nonlinear optimization program. Simulation models describing changes in particle size and concentration enter into the ...
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Journal articleJournal American Water Works Association · January 1, 1987
The costs of granular activated carbon (GAC) filter-adsorbers (second-stage GAC filtration) were compared with those of the sand replacement option (first-stage GAC filtration). Simulation models of total organic carbon (TOC) adsorption and particle remova ...
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Journal articleundefined · December 1, 1986
An optimization model was used to identify least cost contact filtration designs of filtration rate and runtime as a function of raw water particle concentration and average diameter. The optimization model incorporates a previously developed simulation mo ...
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