Glass-like phonon scattering from a spontaneous nanostructure in AgSbTe2.

Journal Article

Materials with very low thermal conductivity are of great interest for both thermoelectric and optical phase-change applications. Synthetic nanostructuring is most promising for suppressing thermal conductivity through phonon scattering, but challenges remain in producing bulk samples. In crystalline AgSbTe2 we show that a spontaneously forming nanostructure leads to a suppression of thermal conductivity to a glass-like level. Our mapping of the phonon mean free paths provides a novel bottom-up microscopic account of thermal conductivity and also reveals intrinsic anisotropies associated with the nanostructure. Ground-state degeneracy in AgSbTe2 leads to the natural formation of nanoscale domains with different orderings on the cation sublattice, and correlated atomic displacements, which efficiently scatter phonons. This mechanism is general and suggests a new avenue for the nanoscale engineering of materials to achieve low thermal conductivities for efficient thermoelectric converters and phase-change memory devices.

Full Text

Duke Authors

Cited Authors

  • Ma, J; Delaire, O; May, AF; Carlton, CE; McGuire, MA; VanBebber, LH; Abernathy, DL; Ehlers, G; Hong, T; Huq, A; Tian, W; Keppens, VM; Shao-Horn, Y; Sales, BC

Published Date

  • June 2, 2013

Published In

Volume / Issue

  • 8 / 6

Start / End Page

  • 445 - 451

PubMed ID

  • 23728075

Electronic International Standard Serial Number (EISSN)

  • 1748-3395

International Standard Serial Number (ISSN)

  • 1748-3387

Digital Object Identifier (DOI)

  • 10.1038/nnano.2013.95

Language

  • eng