Identifying single molecular ions by resolved sideband measurements.
Publication
, Journal Article
Goeders, JE; Clark, CR; Vittorini, G; Wright, K; Viteri, CR; Brown, KR
Published in: The journal of physical chemistry. A
October 2013
The masses of single molecular ions are nondestructively measured by cotrapping the ion of interest with a laser-cooled atomic ion, (40)Ca(+). Measurement of the resolved sidebands of a dipole forbidden transition on the atomic ion reveals the normal-mode frequencies of the two ion system. The mass of two molecular ions, (40)CaH(+) and (40)Ca(16)O(+), are then determined from the normal-mode frequencies. Isotopes of Ca(+) are used to determine the effects of stray electric fields on the normal mode measurement. The future use of resolved sideband experiments for molecular spectroscopy is also discussed.
Duke Scholars
Published In
The journal of physical chemistry. A
DOI
EISSN
1520-5215
ISSN
1089-5639
Publication Date
October 2013
Volume
117
Issue
39
Start / End Page
9725 / 9731
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics
Citation
APA
Chicago
ICMJE
MLA
NLM
Goeders, J. E., Clark, C. R., Vittorini, G., Wright, K., Viteri, C. R., & Brown, K. R. (2013). Identifying single molecular ions by resolved sideband measurements. The Journal of Physical Chemistry. A, 117(39), 9725–9731. https://doi.org/10.1021/jp312368a
Goeders, James E., Craig R. Clark, Grahame Vittorini, Kenneth Wright, C Ricardo Viteri, and Kenneth R. Brown. “Identifying single molecular ions by resolved sideband measurements.” The Journal of Physical Chemistry. A 117, no. 39 (October 2013): 9725–31. https://doi.org/10.1021/jp312368a.
Goeders JE, Clark CR, Vittorini G, Wright K, Viteri CR, Brown KR. Identifying single molecular ions by resolved sideband measurements. The journal of physical chemistry A. 2013 Oct;117(39):9725–31.
Goeders, James E., et al. “Identifying single molecular ions by resolved sideband measurements.” The Journal of Physical Chemistry. A, vol. 117, no. 39, Oct. 2013, pp. 9725–31. Epmc, doi:10.1021/jp312368a.
Goeders JE, Clark CR, Vittorini G, Wright K, Viteri CR, Brown KR. Identifying single molecular ions by resolved sideband measurements. The journal of physical chemistry A. 2013 Oct;117(39):9725–9731.
Published In
The journal of physical chemistry. A
DOI
EISSN
1520-5215
ISSN
1089-5639
Publication Date
October 2013
Volume
117
Issue
39
Start / End Page
9725 / 9731
Related Subject Headings
- 5102 Atomic, molecular and optical physics
- 3407 Theoretical and computational chemistry
- 3406 Physical chemistry
- 0307 Theoretical and Computational Chemistry
- 0306 Physical Chemistry (incl. Structural)
- 0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics