Front-Mediated Melting of Isotropic Ultrastable Glasses.


Journal Article

Ultrastable vapor-deposited glasses display uncommon material properties. Most remarkably, upon heating they are believed to melt via a liquid front that originates at the free surface and propagates over a mesoscopic crossover length, before crossing over to bulk melting. We combine swap Monte Carlo with molecular dynamics simulations to prepare and melt isotropic amorphous films of unprecedendtly high kinetic stability. We are able to directly observe both bulk and front melting, and the crossover between them. We measure the front velocity over a broad range of conditions, and a crossover length scale that grows to nearly 400 particle diameters in the regime accessible to simulations. Our results disentangle the relative roles of kinetic stability and vapor deposition in the physical properties of stable glasses.

Full Text

Duke Authors

Cited Authors

  • Flenner, E; Berthier, L; Charbonneau, P; Fullerton, CJ

Published Date

  • October 2019

Published In

Volume / Issue

  • 123 / 17

Start / End Page

  • 175501 -

PubMed ID

  • 31702270

Pubmed Central ID

  • 31702270

Electronic International Standard Serial Number (EISSN)

  • 1079-7114

International Standard Serial Number (ISSN)

  • 0031-9007

Digital Object Identifier (DOI)

  • 10.1103/physrevlett.123.175501


  • eng