Stereoselective Synthesis of 3-Exo-Substituted 2-endo-Acyl-5-norborene Derivatives
The stereoselective addition of a variety of nucleophiles (ROH, RSH) to several 2-acylnorbornadienes provides an efficient synthesis of the title compounds. The allyl ethers derived from the addition of allyl alcohol are stable to many synthetic transformations and readily liberate the 3-exo alcohol on reductive cleavage. © 1974, American Chemical Society. All rights reserved.
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