Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene
Publication
, Journal Article
Dema, AC; Lukehart, CM; McPhail, AT; McPhail, DR
Published in: Journal of the American Chemical Society
January 1, 1990
When Ph2Si(C≡CCMe3)2 is treated with a cationic Pt-H reagent, a 4-alkylidene-1-silacyclobutenyl ring system is formed. Evidence for the presence of two intermediates in this reaction sequence is obtained by using selective trapping reactions. Acetic acid cleaves at Pt-C bond to give alkenylsilane products, indicating the intermediate formation of a Pt, Si-u-alkenylidene complex. ROH reagents react with a proposed bis(alkylidene)silacyclopropane intermediate to initiate ring opening and to form η3-butadienyl complexes (where R = H, Me, Et, or Ph). The structure of one of these complex ions (R = H) has been confirmed by X-ray crystallography. © 1990, American Chemical Society. All rights reserved.
Duke Scholars
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1990
Volume
112
Issue
20
Start / End Page
7229 / 7233
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences
Citation
APA
Chicago
ICMJE
MLA
NLM
Dema, A. C., Lukehart, C. M., McPhail, A. T., & McPhail, D. R. (1990). Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene. Journal of the American Chemical Society, 112(20), 7229–7233. https://doi.org/10.1021/ja00176a023
Dema, A. C., C. M. Lukehart, A. T. McPhail, and D. R. McPhail. “Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene.” Journal of the American Chemical Society 112, no. 20 (January 1, 1990): 7229–33. https://doi.org/10.1021/ja00176a023.
Dema AC, Lukehart CM, McPhail AT, McPhail DR. Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene. Journal of the American Chemical Society. 1990 Jan 1;112(20):7229–33.
Dema, A. C., et al. “Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene.” Journal of the American Chemical Society, vol. 112, no. 20, Jan. 1990, pp. 7229–33. Scopus, doi:10.1021/ja00176a023.
Dema AC, Lukehart CM, McPhail AT, McPhail DR. Evidence for a Bis(alkylidene)silacyclopropane Intermediate in the Platinum-Mediated Formation of a Silacyclobutene. Journal of the American Chemical Society. 1990 Jan 1;112(20):7229–7233.
Published In
Journal of the American Chemical Society
DOI
EISSN
1520-5126
ISSN
0002-7863
Publication Date
January 1, 1990
Volume
112
Issue
20
Start / End Page
7229 / 7233
Related Subject Headings
- General Chemistry
- 40 Engineering
- 34 Chemical sciences
- 03 Chemical Sciences